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烯烃氢甲酰化用铑-膦均相络合催化剂的合成、表征及热化学性质 被引量：1

Synthesis,Characterization and Thermal Chemical Properties of Rhodium-Phosphine Complexes for Hydroformylation of Alkenes
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摘要 三(三苯基膦)羰基氢化铑(Ⅰ)、反式-双(三苯基膦)羰基氯化铑(Ⅰ)两种铑-膦络合物被广泛用作烯烃氢甲酰化反应的催化剂。通过改进的合成工艺合成了这两种络合物,产率高于文献报道值。通过元素分析、质谱、红外光谱和核磁共振氢谱对两种络合物进行化学结构分析,以及热重-差热分析对这两种络合物进行了热化学性质测定。 Carbonylhydridotris（triphenylphosphine）rhodium（Ⅰ）[HRh（CO）（PPh3）3],trans chlorocarbonylbis（triphenylphosphine）rhodium（Ⅰ） [trans-RhCl（CO）（PPh3）2] are widely used as the catalysts for hydroformylation of alkenes.In this paper,these two compounds were synthesized by improved methods and their yields were higher than that reported in the literatures.The chemical structures of these complexes were determined by elemental analysis,MS,IR and 1H-NMR.The thermal chemical properties were studied via TG-DTA.
作者 张俊 余尧 叶青松 谌喜珠 常桥稳 刘伟平
机构地区 昆明贵金属研究所
出处 《贵金属》 CAS CSCD 北大核心 2010年第3期32-37,共6页 Precious Metals
基金 云南省重大科技计划项目(2008IA008,2008CF002) 昆明贵金属研究所研究与开发(R&D)基金(GY-08-RD17)
关键词 物理化学 烯烃氢甲酰化 铑-膦络合物 合成 结构特征 热化学性质 physical chemistry hydroformylation of alkenes rhodium-phosphine complexes synthesis structure characterization thermal chemical properties
分类号 O643.36 [理学—物理化学]
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参考文献7

  • 1王俐.国外工业氢甲酰化的现状和发展[J].现代化工,2002,22(8):53-58. 被引量：16
  • 2Beller M,Cornils B.Progress in hydroformylation and carbonylation[J].J Mol Catal A,1995,104:17-85.
  • 3潘再富,刘伟平,陈家林,夏永明.铂族金属均相催化剂的研究和应用[J].贵金属,2009,30(3):42-49. 被引量：25
  • 4Ahmad N,Robinson S D,Uttley M F.Transition-metal complexes containing phosphorus ligands:Part Ⅶ.New and improved syntheses of some triphenylphosphine complexes of rhodium,iridium,ruthenium,and osmium[J].J Chem Soc Dalton Trans,1972,7:843-847.
  • 5Chatt J,Shaw B L.Rhodium(Ⅰ) and rhodium(Ⅲ) carbonyl complexes containing tertiary phosphines or tertiary arsines and halogen formed by the decarbonylation of alcohols and by the direct use of carbon monoxide[J].J Chem Soc,1966,10:1437-1442.
  • 6Bath S S,Vaska L.Five-coordinate hydrido-carbonyl complexes of rhodium and iridium and their analogy with CoH(CO)4[J].J Am Chem Soc,1963,85(21):3500-3501.
  • 7廖新丽 姚春香 袁友珠 等.水溶性铑膦配合物HRh(CO)(TPPTS)3及其相关体系的1H-NMR研究.分子催化,1999,13(5):321-326.

二级参考文献51

  • 1中国工程院.中国科学技术前沿[M].北京:高等教育出版社,2000:245-265.
  • 2王尚俊,孙俊全.催化剂工程导论[M].第二版.北京:化学工业出版社,2006:4-9.
  • 3Twigg M V.Catalyst Handbook[M].London:Manson Publishing,1996:470-489.
  • 4Colquhoun H M,Holton J,Thompson D J,et al.New pathway for organic synthesis-practical application of transition metal complexes[M].New York:Springer,1984:345-480.
  • 5Osborn J A,Jardine F H,Young J F,et al.The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives[J].J Chem Soc A,1966:1711-1732.
  • 6Ireland R E,Bey P.Homogeneous catalytic hydrogenation:dihydrocarvone[J].Org Synth Coll,1988,6:459-459.
  • 7Jourdant A,González-Zamora E,Zhu J.Wilkinson's catalyst catalyzed selective hydrogenation of olefin in the presence of an aromatic nitro function:A remarkable solvent effect[J].J Org Chem,2002,67:3163-3164.
  • 8Colquhoun H M,Thompson D J,Twigg M V.Carbonylation-direct synthesis of carbonyl compounds[M].New York:Springer,1991.
  • 9Blum J,Oppenheimer E,Bergmann E D.Decarbonylation of aromatic carbonyl compounds catalyzed by rhodium complexes[J].J Am Chem Soc,1967,89:2338-2341.
  • 10Ohno K,Tsuji J.Organic synthesis by means of noble metal compounds.XXXV.Novel decarbonylation reactions of aldehydes and acyl halides using rhodium complexes[J].J Am Chem Soc,1968,90:99-107.

共引文献39

同被引文献27

  • 1刘良红,傅送保,朱泽华,吴明.苯加氢制备环己烷工艺进展[J].化工进展,2004,23(6):673-676. 被引量：13
  • 2傅送保,段燕凌,任军,刘郁东,朱泽华,闵恩泽.镍基均相络合催化剂苯加氢反应动力学研究[J].石油化工,2006,35(8):745-748. 被引量：10
  • 3李绍芬 刘邦荣 高文新 等.在工业镍催化剂上苯气相加氢反应动力学[J].化工学报,1982,(4):337-347.
  • 4CINNEIDE A D O, HRONEC M, CVENGROSOVA Z, et al. Hydrogenation of benzene to cyclohexene over polymer-supported ruthenium catalysts [ J ]. J Mol Cat A, 1996, 105:25.
  • 5ERHAN A A, FREITAS M A, FIGUEIREDO J L. Bi- metallic Pt-Sn catalysts supported on activated carbon 1 : The effects of support mondification and impregnation strategy [ J ]. Applied Catalysis A : General,2000,192:29.
  • 6FUJIKAWA T, IDEI K, OHKI K, et al. Kinetic behav- ior of hydrogenation of aromatics in diesel fuel over silica- alumina-supported bimetallic Pt-Pd catalyst [ J ]. Applied Catalysis A : General, 2001,205:71.
  • 7PLASSERAUD L, SISSS FINK G. Catalytic hydrogena- tion of benzene derivatives under biphasic conditions [ J]. J Organomet Chem, 1997,539 : 163-170.
  • 8MIAOSD, LIUZM, HAN BX, et al. Runanoparti- cles immobilized on montmorillonite by ionic liquids: a highly efficient heterogeneous catalyst for the hydrogena- tion of benzene [ J ] . Angew Chem, 2006, 118:272 -275.
  • 9ZHANG L, WANG L, MA X Y, et al. Catalytic proper- ties of Ru-'q6-C6 H6-diphosphine complexes for hydrogena- tion of benzene in aqueous-organic biphasie system [ J ]. Catal Commun, 2007, 8(12) : 2238-2242.
  • 10SINGH U K, VANNICE M A. Kinetic and thermody- namic analysis of liquid-phase benzene hydrogenation [ J ]. AIChE J, 1999,45 ( 5 ) : 1059-1071.

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贵金属
2010年 第3期

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