摘要
在有机化合物分子内引入CO的羰基化反应因具有"原子经济性"反应的高选择性和对环境友好而备受学术界及工业界关注。作者通过典型实例综述了氢甲酰化、氢酯基化、氢羧基化及不对称羰基化反应的研究与应用进展。对羰基化反应的催化剂和催化反应机理进行了探讨。
Carbonylation,the direct incorporation of carbonyl into organic molecules,has attracted broad attention from the academic circles and the industrial world because of the high selectivity and the environment friendliness of ＂the atomic efficiency＂.This paper described the study and application of hydroformylation,hydroesterfication,hydrocarhoxylation and asymmetric carbonylation through typical examples.The catalyst and reaction mechanism have been discussed.
出处
《化工科技》
CAS
2011年第2期49-54,共6页
Science & Technology in Chemical Industry
基金
国家自然科学基金(20776071)
青岛科技大学引进人才启动基金
关键词
羰基化反应
羰基钴
氢甲酰化
氢酯基化
氢羧基化
不对称羰基化
Carbonylation
Cobalt carbonyl
Hydroformylation
Hydroesterfication
Hydrocarhoxylation
Asymmetric carbonylation
