摘要
用停流法研究了2，9，16，23-四羧基钴（Ⅱ）酞菁与2-巯基乙醇轴向配位的快速反应动力学，提出了较为合理的反应机理，用非线性及线性拟合的方法求得了各基元步骤的动力学参数，探讨了温度、pH等因素对反应的影响．
The kinetic studies on the acial coordination reaction of Co(Ⅱ)-2,9,16,23-tetracaboxyphthalocyamine with 2-mercaptoethanol in aqueous solution were studied by stopped flow method. A general mechamism was proposed and the kinetic parameters were obeamd by non-liner and liner least-squares program. The effects of temperature and pH on the reaction were investigated in this paper.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1999年第2期167-172,共6页
Acta Physico-Chimica Sinica
基金
国家自然科学基金!29571019
天津市自然科学基金
关键词
钴酞菁
巯基乙醇
氧化
催化剂
Co(Ⅱ)-Phthalocyamine Thiol,Kinetics of axial coordinational reaction, stopped flow method, Mechanism
