摘要
采用分光光度法研究了四磺化酞菁钴（ＣｏＴＳＰｃ）在水、醇－水（ＭｅＯＨ、ＥｔＯＨ、ＰｒＯＨ）、胶束（ＴｒｉｔｏｎＸ－１００）、微乳液（ＴｒｉｔｏｎＸ－１００－壬烷－正戊醇－水）、乙二胺（ｅｎ）、氨水（ＮＨ３）、氰化钾（ＫＣＮ）的水溶液中的二聚现象，测定了ＣｏＴＳＰｃ的二聚常数ＫＤ及ＣｏＴＳＰｃ与ｅｎ、ＮＨ３、ＣＮ－形成配合物的稳定常数Ｋ和生成反应速率常数ｋ。
The dimerization of cobalt tetrasulfonate phthalocyanine(CoTSPc) was studied in the microemulsion,micelles and aqueous alcoholic solutions.The coordination reaction for the formation of complexes CoTSPc( L ) 2,which was formed by cobalt tetrasulfonate phthalocyanine(CoTSPc)plus ligand L(L= NH 3,CN -,en ) ,was also studied.The reaction kinetics was discussed and the stability constant K of CoTSPc( L ) 2 was also calculated from absorbance measurement.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1999年第1期112-114,共3页
Spectroscopy and Spectral Analysis
基金
江苏省教委自然科学基金
