摘要
用１ＨＮＭＲ、ＭＳ方法研究了环戊二烯钠与环氧氯丙烷反应产物的结构，测试表明该反应产物不含环氧基，而是一种螺环化合物，即１螺环［２，４］４，６庚二烯基甲醇。通过ＮＭＲ和ＤＴＡ分析考察了该化合物的二聚及解二聚特性。
The structure of the reaction product of cyclopentadienylsodium and epichlorohydrin was characterized by NMR and MS methods. It was found that there is no epoxy group in the reaction product and the product is 1 spiro 2, 4 hepta 4, 6 dienyl methanol. Dimerization/dedimerization behavior of the obtained compound was also investigated by NMR and DTA tests.
出处
《北京化工大学学报（自然科学版）》
EI
CAS
CSCD
1998年第4期37-41,共5页
Journal of Beijing University of Chemical Technology(Natural Science Edition)
基金
国家自然科学基金
中国石化总公司基础研究基金
