期刊文献+

聚苯胺接枝多壁碳纳米管复合材料的结构与性能研究 被引量:3

Study on Structure and Performance of Polyaniline Grafted Multi-walled Carbon Nanotubes Composites
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摘要 多壁碳纳米管(MWNTs)经对苯二胺功能化后,通过原位聚合及去掺杂反应,首次制备了能在N-甲基吡咯烷酮(NMP)中稳定溶解的本征态聚苯胺(EB)接枝MWNTs(EB-g-MWNTs)复合材料。复合材料中EB与p-MWNTs通过酰胺键连接,形成以p-MWNTs为核、EB为壳的纳米结构,并且EB的结构规整度提高;当该复合材料溶解在NMP中时,溶解度为33.72mg/mL,稳定性好,至少可保存1个月。 After multi walled carbon nanotubes(MWNTs) are functionalized with p-phenylenediamine, polyaniline emeraldine base(EB) grafted MWNTs(EB-g-MWNTs) composite with high solubility and stability in N-methyl-2- pyrrolidinone(NMP) is synthesized by in situ polymerization followed by de-doping for the first time. EB chains link with p-MWNTs via amide bond, core(p-MWNTs)-shell(EB) nano-struetures are formed and crystalline order of EB coatings are enhanced in the nano-composite. EB-g-MWNTs composite achieves improving stability for at lest one month and solubility of 33.72mg/mL in NMP.
出处 《材料导报》 EI CAS CSCD 北大核心 2010年第2期33-37,共5页 Materials Reports
基金 中国民航大学科研基金资助项目(07KYS06) 中央高校基本科研业务费中国民航大学2009年度专项资助项目(ZXH-2009D008)
关键词 聚苯胺 多壁碳纳米管 纳米复合材料 结构 性能 polyaniline, muhi-watled carbon nanotubes, nano-composite, structure, performance
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参考文献20

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同被引文献31

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