摘要
报道了６－二茂铁基－２，２－联吡啶（ｆｃｂｐｙ）配体和４－二茂铁基－２，２，６，２″－联三吡啶（ｆｃｔｐｙ））的Ｍｎ（Ｉ）配合物１（［Ｍｎ（ＩＩ）（ｆｃｔｐｙ）２］（ＣｌＯ４）２·２Ｈ２Ｏ）的晶体结构．电化学研究结果显示：联多吡啶取代基的吸电子诱导效应使二茂铁部分的氧化电位发生了明显的正移．
The syntheses and crystal structures of two ferrocene conjugated polypyridine ligands (6 ferrocenyl 2, 2 bipyridyl (fcbpy) and 4 ferrocenyl 2, 2,6, 2″ terpyridine (fctpy) )and Mn(II) complex of fctpy(1) were described in this work. The electrochemical investigations of two ligands reveal that substitution of the polypyridyl group onto ferrocene causes a positive shift in the redox potential of ferrocene unit and the comparison of the structures of the complex 1 and free ligand fctpy shows that introduction of Mn(II) ion into the ligand does not significantly influence the structure of the ligand.
出处
《武汉大学学报（自然科学版）》
CSCD
1998年第4期452-457,共6页
Journal of Wuhan University(Natural Science Edition)
关键词
二茂铁
电化学
联多吡啶
锰配合物
ferrocene
electrochemistry
polypyridine
Mn(II) complex
