期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

一种新的手性单氢钌配合物的合成 被引量：1

Synthesis of a novel chiral ruthenium hydride complex
在线阅读 下载PDF
导出
摘要 Ru(PPh3)3HCl与(R,R)-1,2-二苯基乙二胺反应生成配合物RuH((R,R)-PhCHNH2CHNH2Ph)(PPh3)2Cl,通过该配合物与三(1-吡唑基)硼氢化钾反应合成了一种新的手性单氢钌配合物TpRuH((R,R)-PhCHNH2CHNH2Ph).合成的钌配合物分子结构经FT-IR、NMR和EA证实. A novel chiral rethenium hydride complex was synthesized by potassium hydrotris（pyrazolyl） borate and RuH（（R,R）-PhCHNH2CHNH2Ph）（PPha）2Cl complex which prepared by Ru（PPha）HC1 and （R, R）-1, 2-diphenylenediamine. The molecular structures of two synthesized complexes were confirmed by FT-IR, NMR spectra and elemental analysis.
作者 尹传奇 杜小秋 冯权武
机构地区 武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室湖北省新型反应器与绿色化学工艺重点实验室
出处 《武汉工程大学学报》 CAS 2009年第7期4-8,共5页 Journal of Wuhan Institute of Technology
基金 湖北省自然科学基金(No.2006ABA282) 湖北省教育厅基金(No.D200615005)
关键词 手性二胺配体 手性单氢钌配合物 比旋光度 chiral diamine ligand chiral ruthenium hydride complex specific rotation
分类号 O626.11 [理学—有机化学] TQ032.41 [化学工程]
  • 相关文献

参考文献29

  • 1Ojima I,Clos N,Bastos C.Recent advances in catalytic asymmetric reactions promoted by transition metal complexes[J].Tetrahedron,1989,45 (22):6901-6939.
  • 2Nozaki H,Moriuti S,Noyori R.Preparation and photochemical isomerization of 2-cyclododecenones[J].Tetrahedron,1966,22(4):1207-1212.
  • 3Vineyard B D,Knowles W S,Sabacky M J,Bachman G L,Weinkauff D J.Asymmetric hydrogenation.Rhodium chiral bisphosphine catalyst[J].J Am Chem Soe,1977,99(18):5946-5952.
  • 4Guo R,Lough A J,Morris R H,et al.Asymmetric hydrogenation of ketones catalyzed by ruthenium hydride complexes of a beta-aminophosphine ligand derived from norephedrine[J].Organometallics,2004,23 (23):5524-5529.
  • 5Abdur-Rashid K,Guo R,Lough A J,et al.Synthesis of ruthenium hydride complexes containing betaaminophosphine ligands derived from amino acids and their use in the H2-hydrogenation of ketones and imines[J].Adv Syn Catal,2005,347:571-579.
  • 6Watanabe M,Murata K,Ikariya T.Enantioselective Michael reaction catalyzed by well-defined chiral Ru amido complexes:isolation and characterization of the catalyst intermediate,Ru malonato complex having a metal? carbon bond[J].J Am Chem Soc,2003,125 (25):7508-7509.
  • 7Dahlenburg L,Gotz R.Optisch reine-aminophosphane und-aminophosphinite für die komplexkatalysierte reduktion organische carbonylverbindungen.Molekülstrukturen yon[(1 R,2R)-Ph2 PCH (Ph) C H (Me) NH2Me] Cl,(1R,2S)-Ph2 PCH (Ph) CH (Me) NHSO2Me und[-{(1R,2R)-Ph2 PCH(Ph)CH(Me) NHMe-N,P} Rh (4-1,5-C8 H12)] BF4[J].J Organometal Chem,2001,619:88-98.
  • 8Guo R,Elpelt C,Chen X,et al.Modular design of ruthenium catalysts with diamine and BINOL derived phosphinite ligands that are enantiomerically-matched for the effective asymmetric transfer hydrogenation of simple ketones[J].Chem Commun,2005,24:3050-3052.
  • 9Abdur-Rashid K,Faatz M,Lough A J,et al.Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols:direct hydride and proton transfer from chiral catalysts trans-Ru (H)2 (diphosphine) (diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes[J].J Am Chem Soe,2001,123:7473-7474.
  • 10Abdur-Rashid K,Clapham S E,Hadzovic A,et al.Mechanism of the hydrogenation of ketones catalyzed by trans-dihydrido (diamine) ruthenium (Ⅱ) complexes[J].J Am Chem Soc,2002,124:15104-15118.

二级参考文献52

  • 1尹传奇,冯权武,陈瑶,柏正武,李早英.钌配合物催化氢化CO_2生成甲酸反应中的醇促进效应[J].化学学报,2007,65(8):722-726. 被引量：5
  • 2[1]Behr A.Carbon dioxide activation by metal complexes[M].Weinheim.VCH,1988.
  • 3[2]Aresta M,Schloss J V.Enzymatic and model carboxylation and reduction reactions for carbon dioxide utilization[M].Dordrecht,Netherlands:Kluwer Academic Publish,1990.
  • 4[3]Jessop P J,Ikariya T,Noyori R.Homogeneous hydrogenation of carbon dioxide[J].Chem Rev,1995,95(2):259-272.
  • 5[4]Leither W.Carbon dioxide as a raw material:the synthesis of formic acid and its derivatives from CO2[J].Angew Chem,Int Ed Engl,1995,34(20):2207-2221.
  • 6[5]Leither,W.The coordination chemistry of carbon dioxide and its relevance for catalysis:a critical survey[J].Coord Chem Rev,1996,153:257-284.
  • 7[6]Inoue Y,Izumida H,Sasaki S.Catalytic fixation of carbon dioxide to formic acid by transition-metal complexes under mild conditions[J].Chem Lett,1976,(8):863-864.
  • 8[7]Sasaki S,Inoue Y,Hashimoto H.Reaction of carbon dioxide with butadiene catalyzed by palladium complexes.Synthesis of 2-ethylidenehept-5-en-4-olide[J].J Chem Soc,Chem Commun,1976,(15):605-606.
  • 9[8]Jessop P G,Jo6 F,Tai C C.Recent advances in the homogeneous hydrogenation of carbon dioxide[J].Coord Chem Rev,2004,248(21-24):2425-2442.
  • 10[9]Gao Y,Kuncheria J K,.Yap G,et al.The interconversion of formic acid and hydrogen/carbon dioxide using a binuclear ruthenium complex catalyst[J].J Chem Soc,Dalton Trans,2000,(18):3212-3217.

共引文献14

同被引文献14

  • 1Hoskins B F, Robson R. Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [- N ( CH3 )4 ] [Cu'ZnH (CN)4 ] and CuI [-4, 4', 4", 4"- tetracyanotetraphenylmethane]BF4 ~ xC6 H5 NO2 [J]. J Am Chem Soc, 1990, 112(4): 1546-1554.
  • 2Zhao D, Timmons D J, Yuan D, et al. Tuning the topology and functionality of metal-organic frameworks by ligand design [J]. Acc Chem Res, 2011, 44(2): 123-133.
  • 3Bureekaew S, Horike S, Higuchi M, et al. One-di- mensional imidazole aggregate in aluminium porouscoordination polymers with high proton conductivity[J].Nature mater, 2009, 8(10): 831-836.
  • 4Dong Y B, Jiang Y Y, Li J, et al. Temperature-de- pendent synthesis of metal-organic frameworks based on a flexible tetradentate ligand with bidirectional coordination donors[J].J Am Chem Soc, 2007, 129 (15) : 4520-4521.
  • 5Sun R, Wang S, Xing H, et al. Unprecedented 4z64 topological 2-D rare-earth coordination polymers from a flexible tripodal acid with additional amide groups [J].Inorg Chem, 2007, 46 (21), 8451-8453.
  • 6Min T, Zheng B, tMi J, et al. Topology diversity and reversible crystal-to-amorphous transformation properties of 3D cobalt coordination polymers from a series of 1D rodlike dipyridyl-containing building blocks and a flexible tripodal acid with additional amide groups [J]. CrystEngComm, 2010, 12 (1): 70-72.
  • 7Zuo C, Bai J, Sun R, et al. Synthesis, structure, novel topology and reversible crystal-to-amorphous transformation of calcium coordination polymers from a flexible tripodal acid with additional amide groups [J]. Inorg Chim Acta, 2012, 383: 305-311.
  • 8Dodziuk H, Demchuk O, Ko~mifiski W, et al. 1 : 3 Complex betweenII-cyclodextrin and dendrimer with three branches involving four glyeine and one adamantyl group [J]. Pol J Chem, 2003, 77(3): 333-340.
  • 9Sheldrick G M. SHELXTL TM ReferenceManual.- version 6. 10 [M]. Bruker AXS, Madison, WI, 2000.
  • 10Jessiman A S, MacNicol D D, Mallinson P R, et al. Inclusion compound design: the piedfort concept [J]. Chem Commun, 1990(22) :1619-1621.

引证文献1

武汉工程大学学报
2009年 第7期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部