Ca_(4(1+x)/5)Mg_((1+x)/5)Zr_4Si_(2x)P_((6-2x))O_(24)磷酸盐陶瓷材料的制备及力学性能
摘要
以化学纯CaCO3、4 MgCO3.Mg(OH)2.5 H2O、ZrO2、Si O2和(NH4)H2PO4微粉为原料,采用高温固相反应法合成了Ca4(1+x)/5Mg(1+x)/5Zr4Si2xP(6-2x)O24(CMZP)粉体,其中x=0、0.1、0.2、0.3。XRD测试结果表明在400℃下保温2h、1150℃下保温4h,能够合成单相的CMZP粉体,粉体干压成形后经冷等静压处理,在1350℃保温8h能烧结得到相对密度为97.5%的陶瓷试样,其平均抗弯强度为50 MPa。
出处
《山东陶瓷》
CAS
2009年第3期3-5,共3页
Shandong Ceramics
参考文献10
-
1V. Krishnaiah, Jose Joseph, G. Seenivasan, K. V. Govindan Kutty. Cetric study of selected NZP-type of ceramic materials. Journal of Alloys and Compounds. 351(2003)212-216.
-
2liu,Dean--Mo. Thermal diffusivity, specific heat, and thermal conductivity of Ca(1- x) MgxZr4P5O24 ceramic, Materials Science & Engineering B: Solid-Stata Materials for Advanced Technology, ( 1994)94-97.
-
3P. Oikonomou, Ch. Dedeloudis , C. J. Stournaras, Ch. Fti-kos. [NZP] : A new family of ceramics with low thermal expansion and tunable properties. Journal of the European Ceramic Society. 27(2007) 1253-1258.
-
4Ye. V. Bortsova, A. K. Koryttseva. New NZP--phosphates Bo. 5 FeTa(PO4 )3 (where B Ca, Sr, Ba). Syn - thesis, crys-tallochemical investigation and thermal expansion. Journal of Alloys and Compounds. (2008) G Model JALCOM-- 18200,No. of Pages 5.
-
5S. Y. Limaye, D. K. Agrawal, H. A. McKinstry, J. Am. Ceram. Soe. 70(1987)C232.
-
6A. I. Orlova, G. N. Kazantsev, S. G. Samoilov, HighTemp. HighPress. 31 ( 1999) 105.
-
7T. K. Li, D. A. Hirschfled, S. VanAken, Y. Yang, and J. J. Brown. The synthesis, sintering, and thermal properties of Ca(1- x) Mgx Zr4 P6O24 (CMZP) ceramics. Journal of Materials Research. (1993)2954-2967.
-
8liu, Dean- Mo. Grain growth in Ca(1-x) MgxZr4 P6O24 ceramics. Journal of Materials Science. (1993)6353-6356.
-
9Else Breval, Herbert A. McKinstry, and Dinesh K. Agrawal. Synthesis and Thermal Expansion Properties of the Ca(1+x)/2Sr(1+x)/2Zr4 P6-2xSi2xO24 System. Intercollege Materials Research Laboratory, J. Am. Ceram. Soc., (1998) 26-32.
-
10liu, Dean - Mo, Sintering of Ca(1- x) Mgx Zr4 P6O24 ceramics, Journal of Materials Science, (1994) 1507-1513.
-
1周曦亚,周斌扬,胡俊,刘林凤.CaO-SiO_2-R_2O-F系微晶玻璃的制备[J].中国陶瓷,2009,45(2):54-55. 被引量：1
-
2廖学品,贾愚,牛存镇.NZP型低热膨胀及耐热冲击磷酸盐陶瓷材料[J].云南化工,1997(1):1-5. 被引量：3
-
3祝琳华,廖学品,郎小川,杨劲.新型NZP族磷酸盐陶瓷Ca_(1-x)Ba_xZr_4(PO_4)_6的合成及其性能研究[J].云南化工,2000,27(2):15-17. 被引量：1
-
4祝琳华,廖学品,郎小川,杨劲.磷酸盐陶瓷 Ca_(1-x)Ba_xZr_4P_6O_(24)粉体的制备及其分散机理研究[J].材料导报,2001,15(6):65-67.
-
5朗小川,李全喜,廖学品,牛存镇,张云坤.耐热冲击磷酸盐陶瓷材料力学性能的研究[J].云南化工,1998(2):24-27.
-
6廖学品,祝琳华,杨劲,郎小川,赵虹.低热膨胀磷酸盐陶瓷材料Ca_(1-X)Ba_XZr_4(PO_4)_6的合成[J].四川大学学报（工程科学版）,2001,33(2):38-42.
-
7戴红莲,闫玉华,冯凌云,李世普.α-TCP/TECP双相磷酸钙的胶凝特性研究[J].武汉工业大学学报,2001,23(1):30-32.
-
8祝琳华,廖学品,郎小川,杨劲.烧结条件对磷酸盐陶瓷Ca_(1-x)Ba_xZr_4(PO_4)_6力学性能的影响[J].昆明理工大学学报（理工版）,2000,25(6):97-102. 被引量：3
-
9李文虎.锆磷酸盐陶瓷材料的研究进展[J].硅酸盐通报,2011,30(5):1118-1121. 被引量：4
-
10彭家惠,彭志辉,张建新,万体智.磷石膏中可溶磷形态、分布及其对性能影响机制的研究[J].硅酸盐学报,2000,28(4):309-313. 被引量：75
