摘要
采用半连续种子乳液聚合法,合成醋酸乙烯酯/叔碳酸乙烯酯(VAc/Veova10)共聚乳液,考察Veova10的加入量对共聚乳液胶膜的玻璃化转变温度和模量,乳液的粘接性能、稳定性能、黏度及微观状态的影响,结果表明:共聚改性后胶膜的低温脆性得到改善,乳液粘接性能略降低,贮存稳定性、稀释稳定性良好。
A copolymer latex of vinyl acetate（VAc）and vinyl ester of versatic acid（Veova10）was prepared by semi-continuous seeding emulsion polymerization. Some basic properties of the copolymer latex were found to be dependent upon the addition of Veova10. The results showed that： 1） low-temperature brittleness of the latex film was improved; 2） the shear strength of the copolymer latex decreased when the percentage of Veova10 was increased; 3） storage stability and dilution stability the copolymer latex were good when the percentage of Veova10 was below 30% of the total weight of all monomers.
出处
《木材工业》
北大核心
2009年第4期43-46,共4页
China Wood Industry
基金
哈尔滨市攻关项目"E0级排放(不含甲醛和苯)胶黏剂关键技术"(2008AA4B6006)
东北林业大学青年科研基金(09012)
关键词
醋酸乙烯酯
叔碳酸乙烯酯
乳液
胶黏剂
vinyl acetate
vinyl ester of versatic acid
latex
adhesive
