期刊文献+

2-硝基-10-羟基-5,10-二氢磷杂吖嗪-10-氧化物的还原研究

Study on the reduction of compound 2-nitro-10-hy droxy-5,10-dihydrophenophosphazing-10-oxid
在线阅读 下载PDF
导出
摘要 2-nitro-10-hydroxy-5,10-dihydrophenophosphazine-10-oxide can be reduced easily with hydrous hydrazine by Fe/MgO catalyst.The reduced compound was detected by IR and HNMR.It showed that the reduction yield is 94%.The catalyst can be used in reduction for three times.This reduction method has a lower cost,less pollution to environment and suit to the industrializing demand for dye intermediate production. 2-nitro-10-hydroxy-5,10-dihydrophenophosphazine-10-oxide can be reduced easily with hydrous hydrazine by Fe/MgO catalyst. The reduced compound was detected by IR and HNMR. It showed that the reduction yield is 94%. The catalyst can be used in reduction for three times. This reduction method has a lower cost, less pollution to environment and suit to the industrializing demand for dye intermediate production.
出处 《化学研究与应用》 CAS CSCD 北大核心 2009年第6期891-894,共4页 Chemical Research and Application
基金 河南省教育厅自然科学项目(200615003) 开封市自然科学项目(070135)
关键词 2-硝基10-羟基-5 10-二氢磷杂吖嗪-10-氧化物 铁镁滑石催化剂 水合肼 2-nitro-10-hydroxy-5,10-dihydrophenophosphazine-10-oxide Fe/MgO catalyst hydrous hydrazine
  • 相关文献

参考文献5

  • 1Piskunova O. G. , Bokanov A.I. , Stepanov B. Phenophosphazine Ⅲ. Synthesis and reaction of nitro derivatives of 5,10-dihydro-10-hydroxy-5-methylphenophospha-zine 10-oxide.[J]. Gen.Chem. (USSR),1978,48: 1201-1205.
  • 2吴旭,谢鲜梅,杜亚丽,王志忠.水滑石类材料碱性催化性能的应用研究[J].应用化工,2005,34(8):469-472. 被引量:11
  • 3JianYi Shen, Bing Guang, Mai Tu, et al. Preparation and characterization of Fe/MgO catalysts obtained from hydrotalcite-like compounds [ J ]. Catalysis Today, 1996,30:77-82.
  • 4周彤,战可涛,李峰,Evans D.G.,段雪,张密林.层状前体镁铁水滑石及磁性材料的制备及表征[J].无机化学学报,2002,18(8):777-781. 被引量:5
  • 5M. Benz, A. M. Van der Kraan, R. Prins. Reduction of aromatic Litrocompounds with hydrazine hydrate in the presence of an iron oxide hydroxide catalyst Ⅱ. Activity, X-ray diffraction and mossbauer study of the iron oxide hydroxide catalyst[J]. Applide catalysis A, 1998,172 : 149- 157

二级参考文献19

  • 1申延明,张惠,吴静,刘东斌,张振祥.采用HTLcs前驱体制备的丙酮一步法制MIBK催化剂[J].化工科技,2004,12(5):24-27. 被引量:4
  • 2李连生,马淑杰,惠建斌,刘新生,徐如人,包玉敏.稀土水滑石催化合成邻苯二甲酸二戊酯的研究[J].高等学校化学学报,1995,16(8):1164-1167. 被引量:23
  • 3Reichle W T. Catalysts for aldol condensations[ P] . US:498146, 1984-07-03.
  • 4Emildum Itriu, Vasile Hulea, Carmen Chelaru. Influence of the acid-base properties of solid catalysts derived from hydrotalcite-like compounds on the condensation of formaldehyde and acetaldehyde [ J ]. Applied Catalysis A:General, 1999,178 : 145-157.
  • 5Chen Y Z,Hwang C M,Liaw C W. One-step synthesis of methyl isobutyl ketone from acetone with calcined Mg/Al hydrotalcite-supported palladium or nickel catalysts [J].Appl Catal A : General, 1998,169 (2) : 207-214.
  • 6Winter Ferry , Jos Van Dillen A , Krijn P, et al . Singlestage liquid-phase synthesis of methyl isobutyl ketone under mild conditions [J]. Journal of Molecular Catalysis A:Chemical, 2004,219 : 273-281.
  • 7Umberto Costantino, Massimo Curini, Francesca Montanari ,et al. Hydrotalcite-like compounds as catalysts in liquid phase organic synthesis I. Knoevenagel condensation promoted by [ Ni0.73 Al0.27 (OH)2] (CO3) 0.135 [J]. Journalof Molecular Catalysis A : Chemical, 2003,195:245-252.
  • 8Faiz Ahmed Khan, Jyotirmayee Dash, Rashmirekha Satapathy, et al. Hydrotalcite catalysis in ionic liquid medium: a recyclable reaction system for heterogeneous Knoevenagel and nitroaldol condensation [J]. Tetrahedron Letters, 2004,45 : 3055-3058.
  • 9Climent M J , Corma A , Guil-Lopez R , et al. Solid catalysts for the production of fine chemicals & colon; the use of alpon and hydrotalcite base catalysts for the synthesis of arylsulfones[J]. Catal Lett, 1999,59( 1 ) :33-38.
  • 10Boyapati Manoranjan Choudary, Mannepalli Lakshmi Kantam , Chinta Reddy Venkat Reddy, et al. The first example of michael addition catalysed by modified Mg-Al hydrotalcite [J]. Journal of Molecular Catalysis A:Chemical, 1999,46 : 279-284.

共引文献14

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部