摘要
合成了具有良好光合作用抑制活性的标题化合物,测定了其晶体结构.确定了该类化合物的顺反构型,阐明了苯环与氨基间亚甲基对化合物抑制活性的重要作用,解释了氨基氢与酯羰基氧间没有形成氢键的原因.
Based on the structure of D1 protein of photosystem Ⅱ of Pisum sativum , the title compound with good Hill reaction inhibition was designed and synthesized, and its structure was confirmed by X ray diffraction. It was found that the CH 2 group between phenyl and amino is important for compounds inhibition, and there is no H binding in the molecule.
作者
刘华银
扬光富
陆荣健
谭惠芬
杨华铮
来鲁华
LIU Hua-Yin;YANG Guang-Fu;LU Rong-Jian;TAN Hui-Fen;YANG Hua-Zheng;LAI Lu-Hua(The Institute of Elemento Organic Chemistry,National Elemento Organic Chemistry Key Laboratory,Nankai University,Tianjin,300071;The Institute of Physical Chemistry,Peking University,Beijing 1008711)
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第6期899-902,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学青年基金
天津市自然科学基金
