摘要
我们曾用γ－氯丙基键合硅胶（ＣＰＳ），在氢化钠（ＮａＨ）作用下合成了３－（氮杂－１８－冠－６）丙基键合固定相（ＢＣＰ）［１］．该固定相对碱基、核苷酸、硝基苯酚等有较好的分离选择性，但由于ＮａＨ对硅胶基质腐蚀作用较大，导致ＢＣＰ柱效及渗透性较低．本文采...
Aza 18 crown 6)propylsily bonded silica stationary phase for high performance liquid chromatography was prepared via two step solid liquid reaction as follows: porous silica(5￣7 μm) was activated using γ chloropropyl triethoxysilane, then reacted with sodium secondary amine salt of monoaza 18 crown 6. The bonded stationary phase shows a good complexing ability with sodium and potassium ions. The chromatographic behavior of disubstituted benzenes and amino acids was investigated on the bonded stationary phase with various mobile phases.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第5期720-722,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
