摘要
杯芳烃是由对位取代的苯酚在邻位通过亚甲基连接起来的环状化合物，由于具有可调节大小的空腔，不仅能络合无机离子，而且还可络合有机分子，在分析分离方面有极好的应用前景［１，２］．杯芳烃已用于气相色谱［３，４］、离子选择性萃取［５，６］、液相色谱［７，８］和...
,1 Dimethylundecenyloxyphenylmethyl 11,17,23 tri 1',1' dimethylethyl 25,26,27,28 tetrahydroxycalixarene was synthesized from 1,1 dimethylundecenyloxyphenylmethylphenol and bishydroxymethylated p tert butylphenol formaldehyde trimer (3 [3 [3 (hydroxymethyl) 5 tert butylsalicyl] 5 tert butylsalicyl] 5 tert butyl 2 hydroxybenzyl alcohol) by 3+1 fragment condensation in dioxane with TiCl 4 as condensation agent. It was subjected to benzylation with benzyl chloride in NaOH aqueous solution in the presence of Bu 4N +Br as PTC agent. The yield of the tetra o benzylated calixarene was 78%. The tetra o benzylated calixarene and OV 1701 were crosslinked in situ with DCUP onto the surface of fused silica capillary column. The resulted column exhibited high column efficiency(4 379 plates/m, naphthalene 120 ℃) and excellent separation abilities for various positional isomers.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第5期717-719,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
