摘要
阿尔伯塔的油砂资源日益成为北美重要的战略性能源供给.本实验室通过采用碱性条件下在高岭土表面上组装菱沸石的方法,合成了新型的菱沸石-粘土复合材料,并证明此复合材料是比菱沸石更好的油砂沥青精制剂.XRD,SEM,TEM,N2物理吸附和XPS表面元素分析结果表明,菱沸石-粘土复合材料具有大体积烃类分子可及的独特的外表面,该复合材料不仅可降低油砂沥青的裂解反应温度,同时还可大幅度脱除沥青中的硫、氮、镍和钒等杂质.
The Alberta oilsands resource is increasingly recognized as a strategic source for North American energy supply. We synthesized a novel chabazite-clay composite for improved oilsand bitumen upgrading by growing chabazite on kaolin under alkaline conditions. XRD, SEM, TEM, Nz physical adsorption, and XPS surface elemental analysis confirmed that the chabazite-clay composite has a unique exterior surface, accessible to large hydrocarbon molecules, that could moderate bitumen upgrading reaction with high performance contaminant （sulfur, nitrogen, nickel, and vanadium） removal.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2008年第11期1084-1088,共5页
基金
Supported by Alberta Ingenuity Fund of Canada
关键词
油砂
沥青
精制
菱沸石
高岭土
oilsand
bitumen
upgrading
chabazite
kaolin
