期刊文献+

含硅金属化合物 被引量:2

Silicon-Containing Metal Compounds
在线阅读 下载PDF
导出
摘要 近年来,含硅金属化合物由于在催化工业等领域的广泛应用受到了化学工作者的重视。本文综述了以硅原子或硅杂链为配体的桥形成的金属络合物、金属硅氧烷、硅-金属化合物、金属不饱和硅化物和含硅多金属络合物5种含硅金属化合物的研究进展,并对该领域的研究方向提出了展望。 Recently, silicon-containing metal compounds have received much attention because of their extensive applications in catalytic industry and other fields. Five species of silicon-containing metal compounds including metal complexes formed by silicon atom or heterosilicon chain as bridge, metallosiloxanes, silylmetal complexes, metal unsaturated silicon compounds and silicon-containing muhimetallic compounds are introduced in this review. The research tendency of these compounds is prospected.
出处 《化学进展》 SCIE CAS CSCD 北大核心 2008年第11期1651-1658,共8页 Progress in Chemistry
关键词 含硅金属化合物 硅原子桥 金属硅氧烷 金属不饱和硅化物 含硅多金属络合物 silicon-containing metal compounds silicon-bridge metallosiloxanes metal unsaturated silicon compounds silicon-containing muhimetallic compounds
  • 相关文献

参考文献96

  • 1杨帆(Yang F).配位化学(Coordination Chemistry).上海:华东师范大学出版社(Shanghai:East China Normal University Press).2002.2-4.
  • 2Kaliyappan T, Kannan P. Prog. Polym. Sci., 2000, .25: 343-- 370.
  • 3杜作栋(Du ZD),陈剑华(Chen JH),贝小来(Bei XL)周重光(Zhou CG).有机硅化学(Organosilicon Chemistry)北京:高等教育出版社(Bering:Higher Education Press),1990.
  • 4冯圣玉(Feng SY),张洁(Zhang J),李美江(Li MJ),朱庆增(Zhu QZ).有机硅高分子及其应用(Organosilicon Polymer and Applications).北京:化学工业出版社(Bering:Chemical Industry Press),2004.
  • 5Hultzsch K C, Nelson J M, Lough A J, Manners I. Organometallics, 1995, 14:5496--5502.
  • 6Mansel S, Reif U, Prosenc M H, et al. J. Organomet. Chem., 1996, 512:225--236.
  • 7Cuenee T, Royo P. Coord. Chem. Rev., 1999, 193 /195: 447--498.
  • 8Nguyen P, Elipe P G, Manners I. Chem. Rev., 1999, 99: 1515--1548.
  • 9Auner N, Wies J. Organosilicon Chemistry: from Molecules to Materials. VCH: Weinheim, 2003, vol. V.
  • 10Fryzuk M D, Giesbrecht G, Rettig S J. Organometallics, 1996, 15:3329--3336.

二级参考文献29

共引文献7

同被引文献63

  • 1KIRA M,IWAMOTO T. Progress in the chemistry of sta-ble disilenes [J]. Adv Organomet Chem, 2006,54: 73-148.
  • 2OTTOSSON H, EKLOF A M. Silenes ; connectors l)e-tween classical alkenes and nonclassical heavy alkenes[J]. Coord Chem Rev, 2008, 252( 12 - 14) : 1287 -1314.
  • 3LEE V Y, SEKIGUCH1 A. Heteronuclear heavy alkenesEE * ( K, E* = Group 14 Elements) : Gemiasilenes, si-lastannenes, gerinastannenes. next stop [ J ]. Organome-tallics, 2004,23(12) : 2822 -2834.
  • 4LEIGH W J, OWENS T R, BKNOIKOV M,et al. A(*oml)iruM experimental and theoretical study of the kinet-ics and mechanism of the addition of alcohols to electroni-cally stabilized silenes : a new mechanism for the additionof alcohols to the SiC l>ond [J]. J Am Chem Soc, 2006,128(33) ; 10772 — 1()783.
  • 5TOULOKHONOVA I S, GUZEI [ A, WEST R. Synthe-sis of a silene from 1,丨-(lilithiosilole and 2-adamantanone[J]. J Am Chem So(‘,2004, 126( 17) : 5336 -5337.
  • 6TAKEUCHI K, ICHINOHE M, SEKIGUCH丨 A. A newdisilene with 77-accepting groups from the reaction of disi-lyne RSi^SiH ( R =Si;Pr[ CH( SiMe, )2 ] ) with isocya-nides [J]. J Am Chem Soc, 2012, 134(6) : 2954 -2957.
  • 7UPKP:M C, TILLEY T D. Hypercoordinate ketone ad-(kicts of electrophilic r|3—H2SiRH; ligands on rutheniumas key intermediates for efficient and robust catalytichydrosilation [J]. J Atn Chem Soc, 2014,136 ( 46 ):16387 - 16398.
  • 8IWAMOTO T, KOBAYASHI M, UCH1YAMA K, et al.Anthr>l-substituted trialkyldisilene showing distinct intra-molecular charge-transier transition [J]. J Am ChemSoc, 2009,131(9) ; 3156 -3157.
  • 9IWAMOTO T, OHNISHI N, AKASAKA N,et al. An-(hryl-suhstituted 3-silyIene-2-silaaziri(iine obtained l)y i-somerization of (]isiIac*yclopropanimine : an exocyclicsilene showing a distinct intramolecular charge transfertransition [ J ]. J Am Chem Soc, 2013, 135(29):10606 - 10609.
  • 10MAJl'MDAK M,HUGH V,BKJAN 1, el al. Reversi-ble ,complete cleavage of si [ double bond ] si doul)lebonds l)y isocyanide Insertion [ J ]. Angew Chem IntEd, 2013,52(12) : 3516 -3520.

引证文献2

二级引证文献9

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部