摘要
制备了固体超强酸－阳离子树脂负载ＡｌＣｌ３催化剂．探讨了催化乙酸与乙醇酯化反应的最佳工艺条件：催化剂乙酸用量为２８ｇ／ｍｏｌ，酸醇摩尔比为１∶１．２～１∶１．５，反应温度７８℃，反应时间５．０ｈ，催化剂与反应物易分离和再生。
In the paper, the solid superacids cation exchange resin AlCl 3 were prepared and used for synthesising ethyl acetate. It was found that the optimum conditions of the reaction were 78 ℃ for 5 h. The appropriate ratio between acetic acid and ethanol was 1∶1.2-1∶1.5 (mol) and the amount of catalyst added should be 28 g(1 mol acitic acid). The solid superacids catalyst could be easily separated and regenerated from the products, and remained its catalysis activity in reaction time.
出处
《中南民族学院学报（自然科学版）》
1997年第4期49-53,共5页
Journal of South-Central University for Nationalities(Natural Sciences)
