摘要
本文建立了分别以5-Cl-PADAB、5-Br-PADAP作为显色剂测定微量钯的流动注射光度分析法,方法简便快速、重现性好,试剂消耗量少。已用于铂、钯二次精矿中钯的测定,结果良好。
Simple and selective FIA methods based on the reactions between Pd and 5-Cl-PADAB or 5-Br-PADAP are proposed. For single determination 100μl of sampl is required. The linear range was found to be 0—3.0μg/ml for 5-Cl-PADAB and 0—7.0μg/ml for 5-Br-PADAP. The determination limit was found to be 0.05μg/ml for 5-Cl-PADAB and 0.10μg/ ml for 5-Br-PADAP. The working capacity is 120 determinations per hour.The methods were applied to the determination of Pd in ores and good results were obtained.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1989年第3期248-250,共3页
Chinese Journal of Analytical Chemistry
基金
科学基金
关键词
钯
光度法
流动注射
PADAP
Flow injection analysis
Palladium determintion
5-Cl-PADAB and 5-Br-PADAP
