摘要
本文将改进的Scatchard-Hildebrand的溶液理论用于研究在环丁砜含盐溶液中,有机溶质和碱金属盐有特殊相互作用(氢键作用、电荷迁移作用)时,气液色谱保留参数的变化规律。并求得了特殊相互作用平衡常数K_0。
The modified Scatchard -- Hildebrand s solution theory has been used to study the GLC retention behavior of or-gunic solutes in stationary solutions containing salt, which take sulfolane as solvent. In these solutions, some ungener-al molecular interactions between solute and salt exist, such as H--bond interaction, charge transfer interaction. The e-quilibrium constants K. of these interactions have been obtained by GLC.
出处
《河南师范大学学报（自然科学版）》
CAS
CSCD
1990年第3期29-33,共5页
Journal of Henan Normal University(Natural Science Edition)
关键词
气液色谱
非水溶液
溶质
盐
氢键
H-bond interaction
charge transfer interaction
gas liquid chromatography
nonaqueous sloution
