摘要
本文将改进的Scatchard-Hildebrand的溶液理论(MSHT)应用于非水电解质溶液,并应用于研究气液色谱中溶质在含盐混合固定液中保留参数的变化规律。对于溶质—盐无络合作用的体系,MSHT指出:Setschenow的盐效应方程在GLC中成立。另外,本文还由溶质的色谱保留参数和盐在环丁砜中的溶解度数据,计算了MSHT的组分间相互作用参数X_(ij)、l_(ij)。
The modified Scatchard-Hildebrand's solution theory(MSHT)has been used to treat noaqueous electrolyte
solutions,and used to study the GLC retention behavior of organic solutes in stationary solutions containing salt.MSHT shows that the Setschenow's salt effect equation can be used in the systems mentioned above in subtitle studied by GLC.Furthermore,from GLC retention parameters of the solutes and the datas of the solubities of salt in sulfolane,MSHT interaction parameters(x_(i j),l_(i j))have been calculated.
出处
《河南师范大学学报（自然科学版）》
CAS
CSCD
1990年第1期37-42,共6页
Journal of Henan Normal University(Natural Science Edition)
关键词
气液色谱
MSHT
盐效应
环丁砜
MSHT
salt effect
gas-liquid chromatography
sulfolane
