摘要
总结了近几十年来具有工业应用价值的有机硅化学中硅碳键的形成方法——Rochow直接法和硅氢加成法。围绕硅氢加成法,系统阐述了硅氢加成的机理并且介绍了三种表观均相催化剂(Speier催化剂、Karstedt催化剂、铂分子配合物)及异相催化剂。
In the past several decades, several silicon-carbon forming methods in the organosilicon chemistry were developed into industrially valuable processes, including Rochow＇s direct synthesis and the hydrosilylation reaction. A complete review of the mechanism of hydrosilylation was provided, and three apparent homogeneous catalysts （such as Speier＇s catalyst, Karstedt＇s catalyst and platinum molecular complex） and heterogeneous catalysts were introduced.
出处
《有机硅材料》
CAS
2008年第3期171-175,共5页
Silicone Material
关键词
硅氢加成反应
铂
含氢硅烷
烯烃
氯铂酸
乙烯基聚硅氧烷
hydrosilylation, platinum, hydrosilane, alkene, chloroplatinic acid, vinylpolysiloxane
