摘要
采用氯铂酸／异丙醇和三苯基膦／环己酮为催化剂，在室温下能够使三氯硅烷与３－氯丙烯迅速发生硅氢加成反应，高产率地生成３－氯丙基三氯硅烷，继而将３－氯丙基三氯硅烷与无水甲醇同时滴加到沸腾的石油醚中进行醇解。
By using the catalyst composed of chloroplatinic acid/isopropanol and triphenyl phosphine/cyclohexanone, the hydrosilylation of allyl chloride with trichlorosilane took place rapidly in room temperature to give 3 chloropropyltrichlorosilane in 70～80% yield.3 Chloropropyltrimethoxysilane was synthesized through methoxylation of the formed 3 chloropropyltrichlorosilane by dropping simultanously anhydrous methanol and the chlorosilane to boilling petroleum ether.
出处
《合成化学》
CAS
CSCD
1996年第1期85-87,共3页
Chinese Journal of Synthetic Chemistry
关键词
硅氢加成
氯丙基
三氯硅烷
三甲氧基硅烷
Hydrosilylation,3 Chloropropyltrichlorosilane,Methoxylation,3 Chloropropyltrimethoxy silane.
