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云母衬底掺钼二氧化钒薄膜热致相变性能研究 被引量:8

Study on Thermochromic Properties of the Mo-doped VO_2 Thin Films on Muscovite Subtrate
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摘要 采用溶胶凝胶法在云母衬底上制备出掺杂Mo的VO2薄膜,并采用XRD、AFM、XPS、FTIR等检测手段,对掺杂薄膜的物相组成、微观形貌、相变温度进行分析。结果表明:在云母片表面制备出的掺杂的VO2薄膜呈(011)晶面取向生长,并且每增加1%的Mo掺杂量,其相变温度下降7.82℃,掺杂后降低了样品的滞回温宽,而且薄膜相变前后红外透过率的变化量仍保持较高。 In this paper, Mo-doped vanadium dioxide thin films were fabricated on muscovite slice using an inorganic sol-gel method. XRD, AFM, XPS and FTIR were used to investigate the microstructure, morphology and phase transition temperature. The results revealed that VO2 film was (011 ) preferred orientated on muscovite substrate. When the doped Mo ions concentration enhance 1%, the phase transition temperature decreased 7.82 ℃. The temperature width of hysteresis decreased and the orientated VO2 films exhibited excellent optical switching property after Mo doping.
出处 《钢铁钒钛》 CAS 2008年第2期5-8,共4页 Iron Steel Vanadium Titanium
关键词 二氧化钒 薄膜 钼掺杂 相变温度 vanadium dioxide film doped molybdenum phase transition temperature
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参考文献9

  • 1Morin F J. Oxides Which Show a Metal - to- insulator Transition at the Neel Temperature[J]. Physical Review Letters, 1959, (1): 34 -36.
  • 2Guinneton F, Sauques L, Valmalette J C, et al. Comparative Study between Nanacrystalline Powder and Thin Film of Vanadium Dioxide VO2: Electrical and Infrared Properties[ J ]. Physics and Chemistry of solids, 2001,62:1229 - 1238.
  • 3Burkhardt W, Christmann S, Franke T, et al. Tungsten and Fluorine Co - doping of VO2 Films[J]. Thin Solid Films, 2002, ( 1 ) : 226 - 231.
  • 4黄维刚,林华,范樵乔,涂铭旌.掺Mo纳米VO_2粉体的相变特性研究[J].稀有金属材料与工程,2006,35(10):1554-1556. 被引量:14
  • 5Hanlon T J, Coath J A, Richarson M A. Molybdenum - doped Vanadium Dioxide Coating on Glass Produced by the Aqueous Sol - Gel Method[J]. Thin Solid Film, 2003, 436:269 - 272.
  • 6Wu Z P, Miyashita A, Yamamoto S, et al. Molybdenum Substitutional Doping and Its Effects on Phase Transition Properties in Single Crystalline Dioxide Thin Film[J]. Appl Phys, 1999, (9) : 5311 - 5313.
  • 7Xu Shiqing, Ma Hongping, Zhao Kang, et al. Study on Optical and Electrical Swithing Properties and Phase Transition Mechanism of Mo^6+ - doped Vanadium Dioxide Thin Film [ J ]. Material Science, 2004, 39 : 489 - 493.
  • 8沈楠,李毅,易新建.纳米VO_2薄膜的制备及其可见光透过率的改善[J].红外与毫米波学报,2006,25(3):199-202. 被引量:24
  • 9刘向,崔敬忠,梁耀廷,李智.掺钨二氧化钒薄膜的制备与分析[J].真空与低温,2004,10(2):85-88. 被引量:15

二级参考文献17

  • 1王宏臣,易新建,黄光,肖静,陈四海.一种制备氧化钒薄膜的新工艺[J].半导体光电,2003,24(4):280-282. 被引量:11
  • 2潘梅,钟红梅,王少伟,李志锋,陈效双,陆卫.氧含量对VO_(2-x)晶格特性和结构相变影响的研究[J].红外与毫米波学报,2005,24(2):93-96. 被引量:5
  • 3SCHLAG H J, SCHERBER W. New sputter process for VO2 thin films and examination with MIS-elememts and C-V-measurements[J]. Thin Soild Films, 2000, 366:28-31.
  • 4MASATO TAZAWA, PING JIN, TAKESHI MIKI, et al. IR properties of SiO deposited on V1-xWx O2 thermochromic films by vacuum evaporation[J]. Thin Soild Films, 2000,375..100-103.
  • 5Gang Xu, Ping Jin, Masato Tazawa, et al. Optimization of antireflection coating for VO2-based energy efficient window[J]. Solar Energy Materials & Solar Cells, 2004,83(1):29-37.
  • 6Burhard W, Christmann T, Meyer BK. W-and F-doped VO2 films studied by photoelectron spectrometry [J]. Thin Solid Films, 1999,345(2):229-235.
  • 7Jin P, Tazawa M, Keyama M, et al. High quality vanadium dioxide films prepared by an inorganic sol-gel method [J].Materials Research Bulletin, 1996,34 (2):335-340.
  • 8Khan KA, Granqvist CG. Thermochromic sputter-deposited vanadium oxyfluoride coatings with low luminous absorptance[J]. Appl. Phys. Lett,1989,55(1):4-6.
  • 9Lee MH, Cho JS. Better thermochromic glazing of windows with anti-reflection coating [J]. Thin Solid Film,2000,365(1):5-6.
  • 10Burkhardt W, Christmann T, Franke Set al. Thin Solid Film[J],2002, 402:226

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