摘要
用特性粘度([η])和羧值为参数,研究了双唑啉化合物(BOZ)对聚对苯二甲酸乙二酯(PET)的扩链反应动力学过程,表明BOZ是与PET中羧基反应,考察了不同工艺生产的PET的扩链效果。
The coupling reaction kinetics of BOZ on the Poly (ethylene terephthalate)(PET) have been studied by intrinsic viscosity( ) and carboxy value( CV ).The experimental results show that the reaction occurrs between the BOZ and the carboxy group of PET.Effect of chain extension on the PET produced by different technology and factory have been investigated.These results show that the accessihle maximum of products depend on /CV of PET samples.
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
1997年第1期8-13,共6页
Acta Polymerica Sinica
基金
国家自然科学基金
关键词
双恶唑啉
聚酯
PET
扩链
偶联反应
Bioxazoline compound (BOZ),Poly(ethylene terephthalate),Chain extension