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电刷镀含钛合金非晶态镀层的晶化动力学(Ⅱ)

Study of the Crystallization Kinetics of Titanium-Contained Alloy Amorphous Coatings by Brush Plating (Ⅱ)
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摘要 The aim of this paper is to use non-isothermal differental scanning calorimentry tech-nigue (DSC) to study the crystallization kinetics of Ti-Co-Ni-P and Co-Ni-P Noncrystalline coat-ings by electro-brush plating.According to the kinetical study,the crystallization mechamism of two noncrystalline coatings may be expressed by Avrami-Erofeev equation (n=1). The kinetics equation isThe crystallization activation energy E of Ti-Co-Ni-P and Co-Ni-P noncrystaline coatings have been determined. The result shows they are stable noncrystalline alloy. According to the electro-chemical polarization curves, the corrosion resistance of Ti-Co-Ni-P is very good. The aim of this paper is to use non-isothermal differental scanning calorimentry tech-nigue (DSC) to study the crystallization kinetics of Ti-Co-Ni-P and Co-Ni-P Noncrystalline coat-ings by electro-brush plating.According to the kinetical study,the crystallization mechamism of two noncrystalline coatings may be expressed by Avrami-Erofeev equation (n=1). The kinetics equation isThe crystallization activation energy E of Ti-Co-Ni-P and Co-Ni-P noncrystaline coatings have been determined. The result shows they are stable noncrystalline alloy. According to the electro-chemical polarization curves, the corrosion resistance of Ti-Co-Ni-P is very good.
机构地区 贵州大学化学系
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1997年第3期283-287,共5页 Acta Physico-Chimica Sinica
基金 国家自然科学基金 贵州省自然科学基金
关键词 非晶态 镀层 晶化动力学 电刷镀 Ti-Co-Ni-P alloy coatings, Noncrystalline, Crystallization kinetics, Electro-brush Plating
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参考文献5

  • 1姚萍,物理化学学报,1994年,10卷,959页
  • 2宋诗哲,腐蚀电化学研究方法,1994年,12页
  • 3梁志杰,刷镀技术实用指南,1988年
  • 4李余增,热分析,1987年,93页
  • 5郭贻诚,非晶态物理学,1984年,197页

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