期刊文献+

CuCr合金催化剂制备条件对大电流CNTs阴极的影响

Influence of Fabrication of CuCr Alloy Catalyst for Preparation of Carbon Nanotubes as a Large Current Density Cathode
在线阅读 下载PDF
导出
摘要 通过改变溅射功率以磁控溅射法制备了Cu/Cr合金催化剂,研究了化学气相沉积法制备的碳纳米管(CNTs)作为大电流密度场发射阴极的场发射性能。采用扫描电镜和场发射测试仪分别对不同功率催化剂制备的CNTs进行了形貌及性能分析。结果表明,根据溅射功率与催化剂颗粒的关系,可以通过调节溅射功率改变CNTs的长径比及密度,在250WCu/Cr催化剂制备的CNTs薄膜具备了良好的场发射性能,阴极电子发射的开启电场仅为1.47V/μm,当电场为3.23V/μm,发射电流密度可高达3259μA/cm2。 Catalyst is the most important factor in fabricating CNTs by CVD.In this paper,the power of CuCr alloy catalyst by magnetron sputtering method which have effects on the diameter,density,character of CNTs is studied.Based on the theory of grain growth in thin films,the observation by scan electron microscope and I-V characters,it's suggested the adjustment of diameters and densities is possible by changing the power of sputtering on fabrication of CuCr alloy catalyst.The carbon nanotubes with good field emission is obtained.When the power is 250 W,the turn-on field of the CNTs cathode is 1.47 V/μm,and the average current density arrives at 3 259 μA/cm^2 at the applied field 3.23 V/μm.
出处 《液晶与显示》 CAS CSCD 北大核心 2007年第6期708-713,共6页 Chinese Journal of Liquid Crystals and Displays
基金 上海市科委科技攻关项目(No.06DZ11404) 上海市纳米专项(No.0652nm033) 国家自然科学基金(No.50672026) 上海市经委平板显示人才开发项目
关键词 碳纳米管 CuCr催化剂 大电流密度 carbon nanotubes CuCr alloy catalyst large current density
  • 相关文献

参考文献18

  • 1Baker R T K, Hams P S. The Formation of Filament Carbon [M]//Ljubisa R R. Chemistry and Physics of Carbon, New York: Mrcel Dekker Inc. , 1978 : 83.
  • 2Iijima S. Helical microtubules of graphitic carbon [J]. Nature, 1991,354(6348) :56-58.
  • 3耿晓菊,王蜀霞,冯明海.催化剂在碳纳米管制备中的影响[J].材料导报,2006,20(7):112-114. 被引量:10
  • 4朱燕娟,陈玉莲,钟韶,邓颖宇,张国富,张海燕.催化剂的合成方法及配比对CVD法制备碳纳米管的影响[J].浙江师范大学学报(自然科学版),2004,27(3):238-241. 被引量:5
  • 5王常青,孙清,张惠良,沈俭一.催化剂中Cu含量对CVD法制备碳纳米管的影响[J].无机化学学报,2004,20(6):657-662. 被引量:7
  • 6Ma R, Bando Y, Sato T. CVD synthesis of boron nitride nanotubes without metal catalysts [J]. Chem. Phys. Lett. ,2001,337(1-3):61-64 .
  • 7Laurent C,Flahaut E,Peigney A,et al. Metal nanoparticles for the catalytic synthesis of carbon nanotubes [J]. New J. Chem. ,1998,22(11):1229-1237.
  • 8Brotons V,Coq B,Planeix J M. Catalytic influence of bimetallic phases for the synthesis of single-walled carbon nanotubes [J]. J. Molecular Catalysis. A, Chemical, 1997,116(3) :397-403.
  • 9Benito A M, Maniette Y, Munoz E,et al. Carbon nanotubes production by catalytic pyrolysis of benzene [J]. Carbon, 1998,36 (5-6) :681-683.
  • 10Kibria A K M F, Mo Y H,Nahm K S, et al. Synthesis of narrow-diameter carbon nanotubes from acetylene decomposition over an iron-nickel catalyst supported on alumina [J]. Carbon,2002,40 (8): 1241-1247.

二级参考文献124

共引文献46

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部