摘要
本文从实验和理论的角度综述非线性化学反应动力学。介绍了若干非线性化学反应动力学现象如时钟反应、反馈、混合振荡、化学混沌及反应扩散图案等;对时空序列、功率谱、Lyapunov指数、吸引子及其维数、Poincare截面及分叉理论等常用于分析非线性动力学特征的手段作了介绍;探讨了对非线性化学反应的实验装置、测试方法、机理和模型研究的方法;简要回顾了非线性化学反应动力学的发展历史。
The nonlinear chemical reaction kinetics is comprehensively reviewed experimentally and theoretically. Many nonlinear chemical kinetics phenomena such as the clock reaction,feedback, mixed oscillation, chemical chaos and chemical patterns are introduced.The methods of time space series,power spectrum, Lyapunov index, attractors and their dimensions,Poincare section, bifurcation theorem are also discussed. The reactors, measurement, mechanisms and models in nonlinear chemical reaction research are described.
出处
《化学进展》
SCIE
CAS
CSCD
1997年第1期59-68,共10页
Progress in Chemistry
基金
国家自然科学基金
国家教委留学回国人员科研启动基金
关键词
反馈
机理
模型
非线性
化学反应
反应动力学
nonlinear kinetics
feedback
mechanism and model
development of kinetics