摘要
用微型催化反应装置结合吡啶吸附的红外光谱、NH3-程序升温脱附、热重、H2化学吸附和程序升温还原等物理化学手段研究了载体组成对负载型PtSn/ZSM-5催化剂上丙烷脱氢反应性能的影响.结果表明,负载型PtSn/ZSM-5催化剂对丙烷脱氢的催化性能与载体组成密切相关.随着ZSM-5载体中SiO2/Al2O3比的增加,催化剂表面的酸中心总量和强酸中心量逐渐减少.当SiO2/Al2O3摩尔比从45增至108时,催化剂对丙烷脱氢反应的催化活性提高,并且催化剂的积炭量下降.当SiO2/Al2O3摩尔比增至304时,Sn组分与载体ZSM-5之间的相互作用减弱,经H2还原后催化剂中Sn0物种所占的比例增加,导致催化剂H2化学吸附量和丙烷脱氢反应活性下降.
The effect of ZSM-5 composition on catalytic performance of the supported PtSn/ZSM-5 catalyst for propane dehydrogenation was studied using a microreactor combined with infrared spectroscopy of adsorbed pyridine, temperature-programmed desorption of NH3, thermogravimetry, H2 chemisorption, and temperature-programmed reduction. The results showed that the ZSM-5 composition exerted great influence on the catalytic performance of PtSn/ZSM-5 for propane dehydrogenation. With the increase of SiO2/Al2O3 molar ratio in the ZSM-5 support, the numbers of both total and stronger acidic sites decreased. When the SiO2/Al2O3 molar ratio in the ZSM-5 support increased from 45 to 108, the catalytic activity increased, and the amount of coke formed on the catalyst surface decreased. When the SiO2/Al2O3 molar ratio in the ZSM-5 support was higher than 304, the interaction of Sn species with the ZSM-5 support became weaker, and the ratio of Sn^0 species in the catalyst increased after reduction in H2, resulting in the decrease of H2 uptake and catalytic activity of the PtSn/ZSM-5 catalyst for propane dehydrogenation.
出处
《催化学报》
SCIE
CAS
CSCD
北大核心
2007年第11期970-974,共5页
基金
国家重点基础研究发展计划(937计划
2005CB221408).
关键词
铂
锡
ZSM-5分子筛
负载型催化剂
丙烷
脱氢
丙烯
platinum
tin
ZSM-5 zeolite
supported catalyst
propane
dehydrogenation
propylene
