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金属氧化物MoO_3(WO_3)和V_2O_5对烟气脱硝催化性能试验 被引量:8

EXPERIMENTAL STUDY OF CONTRIBUTION OF METAL OXIDE MoO_3(WO_3)AND V_2O_5 ON THE CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NITRIC OXIDE BY AMMONIA
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摘要 以纳米级锐钛型TiO2为载体,负载V2O5和WO3(或MoO3)制备催化剂,研究不同催化剂组分对NO和NO2脱除率以及N2O生成量的影响.结果表明,V2O5的加入使得MoO3(WO3)/TiO2催化剂的活性和选择性得到了改善.MoO3(WO3)的加入主要是改善了催化剂表面的活性位数量,从而使得V2O5/TiO2基催化剂表现出更高的活性. An experimental investigation was conducted to study the contribution of effects of catalyst components on DeNOx performance of V2O5-based Catalyst grafted on nano-grade anatase TiO2. The experiment indicates that MoO3 ( WO3 )/TiO2 are active SCR catalysts even in the absence of V2O5. The presence of V2O5 has significant promoting effect on the activity and selectivity of MoO3 ( WO3 )/TiO2 catalyst. The oxide additive MoO3 ( WO3 ) has increased the reduction of the active vanadia site so that the ternary V2O5-MoO3 (WO3 )/TiO2 show a higher reducibility than the binary V2O5/TiO2 catalyst.
出处 《环境化学》 CAS CSCD 北大核心 2007年第4期439-443,共5页 Environmental Chemistry
基金 教育部新世纪优秀人才资助计划(NCET-05-0469) 中国博士后科学基金(2004035090)资助项目
关键词 V2O5 MOO3 WO3 DENOX V2O5, MoO3, WO3, DeNOx.
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  • 1Amiridis M D,Duevel R V,Wachs I E,The Effect of Metal OxideAdditives on the Activity of V2O5-TiO2 Catalysts for the Selective Catalytic Reduction of Nitric Oxide by Ammonia.Applied Catalysis B:Environmental,1999,20:111-122
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