摘要
研究了丙烯酰基苯并三氮唑(ABT)、甲基丙烯酰基苯并三氮唑(MABT)的光自引发聚合行为及均聚物、共聚物的光化学反应。通过红外光谱、核磁共振谱和元素分析确定了单体、产物的结构,用紫外光谱和自由基捕捉剂探讨了光化学反应机理。
In this paper, we report photopolymerization of acryloylleejotriajole (ABT) and Methy-lacryloylbenetriajole (MABT). It is found that these monomers can be polymerized by self initiation under the irradiation of UV, and formed a product with linear polymers and crosslinking polymers. The mechanism of this polymerzation process has been proved. The structure of monomers and polymers determined by IR, NMR, UV as well as elemental analysis.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1990年第5期83-86,共4页
Polymer Materials Science & Engineering
关键词
ABT
丙烯酰基
苯并三氮唑
聚合
acryloylleejotriajole (ABT) , photopolymerization, photochemicalreactipn.
