摘要
制备了三个含有多个苯环的四氮[14]轮烯合镍(Ⅱ)大环配合物,并将其与Cr(CO)_6反应,合成了四个结构新颖的杂多核配合物,用IR,UV,~1H NMR,^(13)C NMR,MS等波谱表征,确定了化合物的分子结构,并进行了电化学性质的研究.
Four new heteropoly nuclear complexes have been synthesized by the reaction of hexacarbonyl chromium with the tetraaza[14] annulene nickel(II) macrocycles, which have very special structure. All of them have been characterized via EA,IR.UV, 1H NMR,13C NMR,MS. The electrochemical behaviors of these compounds have also been studied by cyclic voltammetry.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1997年第2期160-166,共7页
Acta Chimica Sinica
基金
国家科委重大基础研究项目
国家自然科学基金资助
