摘要
四氮［１４］轮烯类配合物在性质上与卟啉、酞菁类化合物具有许多相似性．本文利用模板反应，合成了２个四氮［１４］轮烯合镍（Ⅱ）配合物及６个四氮［１４］轮烯合镍（Ⅲ）配合物的衍生物，其中６个未见文献报道。对所有化合物进行了ＥＡ、ＩＲ、ＵＶ、１ＨＮＭＲ、ＭＳ等波谱表征．
The property of tetraaza[14] annulene complexes is very similar to that of porphyrin and phthalocyanin compounds. In this paper, two tetraaza[14] annulene nickil (Ⅱ)macrocycles were synthesized by the reaction of template effect,six dibenzoyl tetraaza[14]annulene complexes were prepared by the electrophilic substitutions, which have not been reported before. All were characterized by EA, IR, UV, iH NMR, MS.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1996年第6期854-858,共5页
Chemical Journal of Chinese Universities
基金
国家科学技术委员会重大基础研究项目
国家自然科学基金
关键词
四氮杂环
配合物
镍
四氮轮烯
Tetraaza annulene, Complex, Spectra characterization
