期刊文献+

笼型倍半硅氧烷改性的耐高温厌氧胶 被引量:8

Research on high temperature resistant anaerobic adhesive modified with polyhedral oligomeric silsesquioxane
在线阅读 下载PDF
导出
摘要 以环氧丙烯酸酯为单体,不饱和笼型倍半硅氧烷(POSS)及N-对甲苯基马来酰亚胺(NPTM I)为耐高温改性剂,选择合适的氧化还原体系及其他助剂,制成耐高温厌氧胶,并对其性能进行了相关测试。结果表明,此厌氧胶剪切强度最高达20 MPa,在200℃剪切强度保持率为75%左右,耐高温性能良好。 Using epoxyacrylates as the monomers, unsaturated polyhedral oligomeric silsesquioxane (POSS) and N-p-tolylmaleimide (NPTMI) as the high temperature resistant modifier and selecting a suitable redox initiating system and some other auxiliaries, the high temperature resistant anaerobic adhesive was prepared. The correlated properties of these adhesives were measured. The results showed that the maximum shear strength of the anaerobic adhesive is 20 MPa, and is conserved about 75% compared with room temperature at 200 ℃. This anaerobic adhesive has well high temperature resistant property.
出处 《粘接》 CAS 2007年第3期1-3,12,共4页 Adhesion
基金 河北省自然科学基金项目(E2007000204)。
关键词 笼型倍半硅氧烷 厌氧胶 甲基丙烯酸环氧酯 polyhedral oligomeric silsesquioxane anaerobic adhesive epoxymethacrylate
  • 相关文献

参考文献10

  • 1李桢林,杨志兰,杨蓓,范和平.耐热结构厌氧胶的研制[J].粘接,2005,26(1):4-6. 被引量:4
  • 2张德成,朱荣强,李天书,雷木生.耐高温厌氧胶的研制[J].粘接,2003,24(4):13-14. 被引量:16
  • 3S阿塔瓦拉 GM马瑟拉 HK楚.室温固化的可控强度耐高温厌氧黏合剂组合物[P].CN1265118T.2000-08-30.
  • 4Gao J G,Jiang C J,Zhang X J.Kinetics of curing and thermal degradation of POSS epoxy resin/DDS system[J].Inter J Polym Mater,2007,56:65-77.
  • 5张立培.官能化笼型倍半硅氧烷(POSS)的合成与表征及其环氧树脂复合材料性能研究[Z].北京:北京化工大学,2000.
  • 6吕生华,何洋,王结良,梁国正.环氧(甲基)丙烯酸酯树脂的制备及应用研究[J].材料导报,2003,17(8):82-83. 被引量:10
  • 7杨丽庭,张留成,刘国栋,高俊刚,刘海峰,金日光.N-PMI/MMA/AN乳液共聚物的合成及热分析研究[J].高分子材料科学与工程,2001,17(5):38-41. 被引量:9
  • 8George B,Toryeras F,Grohens Y,et al.Analysis of curing mode and mechanical properties of an anaerobic adhesive[J].Eur Polym J,1998,34:399-404.
  • 9Frederick F,PaulJ.Structural Anaerobic adhesive composition with improved cure speed and strength[P].US 6596808B2,2003-6-22.
  • 10斋藤宏,矾崎正义,安藤秀树.具有官能团的笼型倍半硅氧烷类树脂及其制造方法[P].CN 1504494A,2004-06-16.

二级参考文献14

  • 1.[P].特开平4—117474..
  • 2John G. Susanne Morrill. Claran B. Allylic phenyl ether (meth) acrylate compositions and novel allylic phenyl ether (meth)acrylate mon omers[P]. US6,231,714B1, 2001-5-15.
  • 3Frederick F, Paul J. Structural Anaerobic adhesive composition with improved cure speed and strength[P]. US 6, 596,808B2,2003- 6 - 22.
  • 4Shabbir Attarwala,Richard D Rich, Natalie R Li. Anaerobic compositions with enthaned toughness and crack resistance[P]. US 2003/0036601A1,200a- 2- 20.
  • 5Chiu H T,Wang J H. Dynamic mechanical properties of the chemical oxidation on UHMWPE fibers for imporved adhesion to expoxy resin matrix. J Appl Polym Sci, 1998, 68:1387
  • 6Toshio O, Hiroaki M. Improvement of the mechanical properties of an ultrahigh molecular weight polyethylene fiber/expoxy composite by corona-discharge treatment. J Appl Polym Sci,2001,79:1162
  • 7台会文,姬荣琴.PBT 的 DSC 表观结晶动力学研究[J].河北工业大学学报,1998,27(3):21-28. 被引量:2
  • 8欧召阳,马文石,潘慧铭.环氧树脂改性研究新进展[J].中国胶粘剂,2001,10(2):41-44. 被引量:39
  • 9杨颖泰.厌氧胶的发展动态[J].粘接,2001,22(4):22-23. 被引量:6
  • 10关昶,丁斌,金朝辉,韩运华.新型厌氧性耐高温胶粘剂[J].吉林化工学院学报,2002,19(1):5-8. 被引量:9

共引文献34

同被引文献460

引证文献8

二级引证文献28

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部