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无铅无镉光亮化学镀Ni-P合金 被引量:2

Study on Electroless Bright Nickel-Phosphorous Alloy Plating with Lead-free and Cadmium-free Bath
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摘要 研发了一种无铅无镉的化学镀镍新工艺,以两种新型稳定剂复合使用替代铅和镉,确定稳定剂SY-2的最佳用量为4mg/L镀液在6周期仍保持清澈透明,具有良好的稳定性;镀速在0~6周期之间为27~21μm/h,镀层磷质量分数为5.6%~9.0%,所得镀层光亮、硬度高、孔隙率低,具有良好的结合力和耐腐蚀性。该工艺镀液稳定性和镀层性能在一定程度上已超过了有铅有镉工艺,完全可以作为含铅、镉化学镀镍的替代品。 An EN (electroless nickel) process with lead free and cadmium free was developed, in which two new stabilizers were used to substitute for Pb and Cd. The optimum concentration of stabilizer SY-2 was established as 4 mg/L. The plating bath has a good stability even after 6 MTO, it is still clear. The deposition rate between 0-6 MTO is 27-21μm/h and the P content is 5.6%-9.0%. The EN deposit is bright and it has low porosity, high hardness and high corrosion resistance. The process performance is superior to the process with lead and Cadmium in a certain extent and can work as the substitute for Pb and Cd.
出处 《电镀与精饰》 CAS 2007年第2期27-30,41,共5页 Plating & Finishing
关键词 无铅无镉 化学镀Ni—P 新型稳定剂 lead free and cadmium free electroless Ni-P plating new stabilizer
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参考文献5

  • 1Namboodiri P N N,Prasad K V,Mathur P B.Role of stabilizers in electroless plating baths[J].Transactions of the SAEST,1972,7(3):122-126.
  • 2Rozenblyum R G,Burakov M R,Yakov A A D.Use of stabilizers during chemical nickel plating[J].Zashchita Metallov,1971,7(3):351-353.
  • 3Lanzoni E,Martini C,Ruggeri R,et al.Structure and corrosion behavior of electroless Ni coatings deposited from differrently stabilized baths[J].European Federation of Corrosion Publications,1997,20:232-243.
  • 4Kivel J,Sallo J S.The effect of thiourea on alkaline electroless deposition[J].Journal of the Electrochemical Society,1965,112(12):1201-1203.
  • 5Heber J,Egli A.Electroless nickel plating composition and method of depositing electroless nickel layer[P].Patent:TW226382B.2005-01-11.

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