摘要
采用腔膜法测定Na+在γ-(甲基丙烯酰氧)丙基三甲氧基硅烷(KH570)与甲基丙烯酸羟乙酯(HEMA)及N-乙烯基吡咯烷酮(NVP)共聚物水凝胶角膜接触镜材料中的渗透系数,研究了Na+渗透系数的影响因素。结果表明,Na+在水凝胶膜中的扩散过程为稳态扩散,其渗透系数随温度升高而显著增大,但温度超过60℃,Na+渗透系数的增大幅度显著下降;水凝胶膜中Na+的渗透系数随NVP及KH570质量分数增多而增大,但KH570的质量分数超过15%,Na+的渗透系数反而随KH570含量增多而减小,其原因在于Na+被聚合物中的微孔陷阱捕获而无法跳出。
The penetration coefficient of Na^＋ in copolymer hydrogel membrane of γ- （methacryloyl - oxy） propyltrimethoxysilane （KH 570）, hydroxyethylmethacrylate （HEMA） and N-vinylpyrrolidone （NVP） was measured, and the factors influencing the penetration coefficient of Na^＋ were investigated as well. The results showed that the diffusion process of Na^＋ in the hydrogel was stable diffusion, and the penetration coefficient increased remarkably when the temperature increased, while the increase in penetration coefficient dropped when the temperature was over 60℃. The penetration coefficient increased as the content of KH 570 or NVP increased, while the penetration coefficient decreased as the content of KH 570 was over 15wt%. The reason was Na^＋ being captured by the microholes of the hydrogel.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2007年第4期572-576,共5页
Chemical Industry and Engineering Progress
基金
广东省自然科学基金资助项目(No.5300978)
关键词
含硅水凝胶
Na^+渗透性
腔膜法
接触镜
silicon-containing hydrogel
penetration of Na^＋
cell-membrane method
contact lens
