摘要
Dinuclear copper(Ⅱ) complexes of [2+2] macrocyclic Schiff bases have been prepared from chiral 1,4-diamines using sodium ions as template. Catalytic investigation on the titled complexes has been carried out on model reactions (asymmetric sulfoxidation and asymmetric oxidative-coupling reactions).
Dinuclear copper（Ⅱ） complexes of [2＋2] macrocyclic Schiff bases have been prepared from chiral 1,4- diamines using sodium ions as template. Catalytic investigation on the titled complexes has been carried out on model reactions （asymmetric sulfoxidation and asymmetric oxidative-coupling reactions）.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第7期1345-1348,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.20471027)
江苏省人事厅博士后基金(No.0502005B)资助项目
关键词
双核铜(Ⅱ)
大环席夫碱
1
4-二胺
不对称催化
dinuclear copper（Ⅱ）
macrocyclic Schiff base
1,4-diamines
asymmetric catalysis
