摘要
A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde) -α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.
A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2：5,6-di- O-isopropylidene-3-O-methylene-[5-（3-tert-butyl-2-hydroxy benzaldehyde）]-α-D-glucofuranose with （1R,2R）-1,2- diaminocyclohexane. Several chiral complexes of Mn^3＋、Fe^3＋、Co^2＋ and Cu^2＋ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第6期1133-1136,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20376017)。
