摘要
用１－溴代直链烷，ａ，ω－二溴代烷及１１－溴代十一酸甲酯在铜盐络合物催化剂Ｌｉ２ＣｕＣｌ４的存在下，通过格氏偶合反应合成长链脂肪酸酯类，后者在催化剂氟化铯的存在下，用三乙氧基硅烷还原水解合成长链（奇偶数碳）脂肪族醇类．
The long-chain ester has been synthesized from 1-Bromoalkane, a,ω-Dibromoalkane and 11- Bromoalkanoat (in the presence of Li2CuCl4) by the Grignard coupling reaction,followed by The reduction with Triethoxysilane (in the presence of Cesiumq luoride) to give long chain alcohol.
出处
《厦门大学学报（自然科学版）》
CAS
CSCD
北大核心
1996年第4期560-563,共4页
Journal of Xiamen University：Natural Science
关键词
格氏偶合反应
溴代直链烷
三十烷醇
合成
Grignard coupling reaction, 1-Bromoalkane, α,ω-Dibromoalkane, 11Bromoandecanoate, long-chain alcohol
