摘要
高立方烷-2,4-二羧酸(1)通过Barton脱羧氯化反应,可合成出2,4-二氯高立方烷(3);而通过改进的Hunsdiecker反应,则可分别合成出2,4-二溴高立方烷(4)和2,4-二碘高立方烷(5)。
Homocubane -2,4 - dicarboxylic acid (1) was converted into 2, 4 - dichlorohomocubane (3) by Barton chlorodecarboxylation. 2,4 - dibromohomocubane (4) and 2,4 - diiodohomocubane (5) were synthesized also from 1 by mcxiified Hunsdiecker reaction.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1996年第2期186-188,共3页
Chinese Journal of Organic Chemistry
