摘要
本文就羰基的保护形式之一—肟的脱肟方法作了综述。全面介绍了脱肟基再生为羰基的各种方法之特点,并将它们分为五大类:酸性水解脱肟;还原脱肟;氧化脱肟;电化学脱肟;生物化学脱肟。同时也描述了一些反应的机理。
In this paper, methods of deoximation are reviewed. Oxime was used to protect carbonyl group as one of stable protective groups. Peculiarity of verious deoximation methods for regenerating parent carbonyl group from its oxime have been introduced more widely. These reactions have been classified into five kinds' acid- catalysed hydrolytic, reductive, oxidative, electrochemical, and biochemical. Some deoximation mechanisms are also described.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1996年第2期121-132,共12页
Chinese Journal of Organic Chemistry
关键词
肟
脱肟
裂解
再生
oxime, deoximation, cleavage, regenerationation
