摘要
目的对光茎大黄根的化学成分进行研究。方法采用硅胶柱色谱、重结晶等方法进行分离,利用现代波谱技术(MS,1H-NMR,13C-NMR)及理化性质进行结构鉴定。结果从该植物根中分离并鉴定了5个化合物,分别是:邻苯二甲酸二丁酯(Ⅰ),大黄素-8-O--βD-葡萄糖苷(Ⅱ),芦荟大黄素-3-(羟甲基)-O--βD-葡萄糖苷(Ⅲ),β-谷甾醇-3-O--βD-(6′-十七碳酰基)葡萄糖苷(Ⅳ),山柰酚(Ⅴ)。结论该5个化合物均为首次从该植物中分离得到。
OBJECTIVE To study the chemical constituents in the root of Rheum glabricaule.METHODS Compounds were isolated by various column chrumatographies with silica gel.Their structures were elucidated by spectral analysis（MS,^1H-NMR,^13C-NMR）and chemical evidence.RESULTS Five compounds were isolated from this plant,and identified as dibutyl phthalate （Ⅰ）,emodin-8-O-β-D-glucopyranoside（Ⅱ）,aloc-cmodin-3-（hydroxymethyl）-O-β-D-glucopyranoside（Ⅲ）,β-sitosterol-3-O-β-D-（6′-O-acyl）-glucopyranoside （Ⅳ） and kaempferol（Ⅴ）,respectively.CONCLUSION All above compounds are obtained from this plant for the first time.
出处
《中国药学杂志》
CAS
CSCD
北大核心
2006年第4期253-254,共2页
Chinese Pharmaceutical Journal
关键词
蓼科
光茎大黄
化学成分
Polygonaceae
Rheum glabricaule Sam.
chemical constituents
