摘要
使用一种离子液体[1-乙基-3-甲基咪唑金翁四氟硼酸盐(EM IBF4)]掺杂极性聚合物-偏氟乙烯/六氟丙烯共聚物[P(VDF-HFP)],制备了固态聚合物电解质,其热分解温度达到273℃,30℃的离子电导率达到1-0 4S/cm数量级,对铝集流体具有较好的电化学稳定性。
A kind of ionic liquid, 1-ethyl-3-methylimidazolium tetrafluoroborate（EMIBF,） was used as plasticizer for polar polymerpoly （vinylidenefluoride-co-hexafluorpropylene）[P（VDF- HFP）7. The pyrogenation temperature of this polymer electrolyte adds up to 9.73 ℃. It possesses the ionic conductivity up to the magnitude order of 10^-4 S/cm at 30 ℃. In this paper the effect of amount of lithium salt on ionic conductivity was investigated by electrochemical method. It suggested a possible mechanism for the influence of lithium salt on the ionic conductivity for polymer electrolytes. Moreover, the electrochemical stability of polymer electrolyte was good with respect to Al substrate.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
2006年第1期207-210,共4页
Polymer Materials Science & Engineering
基金
湘潭市科技局资助项目(潭科计字200401)
