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球碳衍生物在钕系催化剂催化丁二烯聚合中的应用──催化剂的相态 被引量:1

APPLICATION OF C60X. IN BUTADIENEPOLYMERIZATION WITH NEODYNIUM CATALYST-PHASE STATE OF CATALYST
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摘要 在Nd(naph)3-Al(i-B3)3-Al(i-Bu)2Cl(简称Nd—Al-Cl)三元催化体系中加入球碳衍生物C60Xn(X为某卤素基因),改善了催化剂的相态稳定性,同时对比考察了几种溶剂对C60Xn的溶解性,发现溶解度都比加氢汽油好,以其催化丁二烯聚合,活性也有所提高。 Phase stability of Nd(naph),-Al(i-Bu)3 - Al(i - Bu)2Cl(abbre.Nd - Al - CI)trinary catalyst system was improved by adding C6oXn Solubility and catalysing activity of C6oXn in severalsolutes (CH2Cl2 and tolene)were compared.Results showed that their solubility was higher thanthat in hydrogenated gasoline.When being used to catalyst butadiene polymerization,the activityincreased
出处 《弹性体》 CAS 1996年第1期12-16,共5页 China Elastomerics
关键词 催化剂 相态 球碳衍生物 丁二烯 聚合 Neodynium catalyst system Phase state C_60X_n
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  • 1刘子阳,高等学校化学学报,1993年,14卷,8期,917页

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