摘要
The interaction of Eu^3+-rutin with CT DNA was studied by UV-visible spectroscopy and electrochemistry. All experimental results indicate that the complex binds to DNA by the electrostatic mode and the groove binding mode. Information such as intrinsic binding costant ( k = 1. 426 × 104 mol·L^-1 ), and binding numbers ( n = 2), were determined by cyclic vohammetry and differential pulse vohammetry at glass carbon electrode. Interaction between Eu^3+ with rutin was also studied by UV-visible spectroscopy.
The interaction of Eu^3+-rutin with CT DNA was studied by UV-visible spectroscopy and electrochemistry. All experimental results indicate that the complex binds to DNA by the electrostatic mode and the groove binding mode. Information such as intrinsic binding costant ( k = 1. 426 × 104 mol·L^-1 ), and binding numbers ( n = 2), were determined by cyclic vohammetry and differential pulse vohammetry at glass carbon electrode. Interaction between Eu^3+ with rutin was also studied by UV-visible spectroscopy.