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多孔圆筒铸铁阳极电解制备高铁酸盐及处理联苯胺模拟废水的研究 被引量:1

Studies of Electro-Generated Ferrate at Porous Cylinder Castiron Anode and Degradated of Bennzidine Wastewater
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摘要 采用双阴极室隔膜电解槽,以多孔圆筒铸铁为阳极电解法制备水处理剂高铁酸盐.实验表明,在14 mol/L的NaOH溶液中,30℃下以30 mA/cm2的电流密度电解5.5 h可以获得36.8%的电流效率,高铁浓度可达到0.07 mol/L.用电解新制的高铁酸盐降解联苯胺模拟废水的结果表明,CODCr的去除率达85%,联苯胺最终被矿化成小分子无机物. Electro-generated water treatment FeO4^2- in diaphram cell with double cathedic chamber and porous cylinder cast iron as the anode has been reported. The experiment result showed that the eletro- effient and the concentration of FeO4^2- were higher by using double cylinder castiron anode. An optium re- sult was obtained at J=30 mA/cm^-2, 30℃, 14 mol/L NaOH, 0.07 mol/L FeO4^2- was producted and the current yield was 36.8 % for 5.5 h electrolysis. The result of ferrate oxidative degradation of benzidine wastewater showed the removal rate of CODCr was more than 85% and the final products were small molecule inorganic compounds.
出处 《福建师范大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第3期27-30,共4页 Journal of Fujian Normal University:Natural Science Edition
基金 福建省自然科学基金资助项目(A9910009)
关键词 高铁酸盐 圆筒铸铁阳极 电流效率 联苯胺 ferrate porous-cylindercastiron anode efficient benzidine
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