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对苯二甲酸根桥联双核铜(Ⅱ)配合物的合成 被引量：7

Synthesis of a novel μ—terephthalato binuclear copper(II) complexes
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摘要 在水溶液中以对苯二甲酸根(TPHA)为桥联配体,端接1,10-邻菲罗啉(phen)合成了一个新的三元混配的配合物[Cu2(TPHA)(phen)4].2ClO4,经元素分析以及红外光谱等手段,推定该配合物具有TPHA桥联双核铜(Ⅱ)结构,铜(Ⅱ)离子处于五配位的四角锥环境. A new terephthalato-bridged binuclear copper （Ⅱ） complex with the formula [Cu2（TPHA）（phen）4·2ClO4, where phen stands for 1, 10 - phenanthroline and TPHA respresents the terephthalate dianions , has been synthesized and characterized. Based on IR and elemental analyses, the complex is proposed to have extened TPHA-bridged structure consisting of two copper（Ⅱ） ions in which each copper（ Ⅱ ）ion has square pyramidal environment with five-coordinated.
作者 毕建洪 熊付超 张悠金
机构地区 安徽教育学院化学系 中国科技大学化学与材料科学学院
出处 《商丘师范学院学报》 CAS 2005年第5期93-95,共3页 Journal of Shangqiu Normal University
基金 国家自然科学基金项目(29871001) 安徽省教育厅自然科学研究项目(2004Kj102)
关键词 对苯二甲酸 双核铜(Ⅱ)配合物 合成 terephthalato binuclear copper（Ⅱ） complex synthesis
分类号 O641.4 [理学—物理化学]
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参考文献9

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同被引文献33

  • 1毕建洪.分子铁磁体研究进展[J].安徽教育学院学报,2005,23(3):66-69. 被引量：1
  • 2程晓丽,胡乃梁,李健.杂大环化合物的合成及应用[J].安徽教育学院学报,2005,23(6):86-89. 被引量：5
  • 3魏太保,王海,林奇,张有明.相转移催化条件下N-芳酰基-N′-芳基硒脲衍生物的合成及其晶体结构[J].高等学校化学学报,2006,27(9):1680-1682. 被引量：7
  • 4程晓丽,姚如富,姚富友,胡乃梁.一种新的席夫碱大环铜配合物的合成与光谱性质研究[J].安徽教育学院学报,2006,24(6):76-77. 被引量：4
  • 5Moulton,B.;Zaworotko,M.Synthesis,Characterization,and Crystal Engineering of[NiII(1,2-Diaminocyclohexane) 3] (N3)Cl:Three-Dirnensional Framework by Hexafurcated N-H Hydrogen Bonds J.Chem.Rev.2001,107,1629-1658.
  • 6Hu Nailiang,Bi Jianhong,Huang Zixiang,Shen Yuhua.Synthesis and structure of a trans-oxpn-bridged binuclear copper(Ⅱ) complex[J].Asian J.Chem.,2005,17 (3),1989-1991.
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  • 8Bi Jianhong,Song Jimei,H uang Zixiang,Wang Yihu,Kong Lingtao,Hu Nailiang.Synthesis and Crystal Structure of the One-dimensional Supramolecular tetaraazamacrocyclic Copper(Ⅱ) Compound[J].Asian J.Chem.;2006,18 (3),2365-2370.
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引证文献7

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商丘师范学院学报
2005年 第5期

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