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CuO/ZrO_2活性组分与载体相互作用及其TPR特性 被引量:17

The Interaction between Active Phase and Support and the TPR Characteristics on CuO/ZrO_2 Catalyst
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摘要 The reduction behavior of CuO supported on ZrO2 and Al2O3 has been investigated by temperature-programmed reduction (TPR) and TG techniques. The oaldation activity of CO on the catalysts has also been studied. It has been found that there is obvious difference between TPR profiles of ZrO2 supported CuO and Al2O3 supported catalysts, the monolayer CuO on ZrO2 is easily reduced, and which leads to a dramatic increase in oxidation activity. The reduction behavior of CuO supported on ZrO2 and Al2O3 has been investigated by temperature-programmed reduction (TPR) and TG techniques. The oaldation activity of CO on the catalysts has also been studied. It has been found that there is obvious difference between TPR profiles of ZrO2 supported CuO and Al2O3 supported catalysts, the monolayer CuO on ZrO2 is easily reduced, and which leads to a dramatic increase in oxidation activity.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1996年第5期464-467,共4页 Acta Physico-Chimica Sinica
基金 浙江省教委基金
关键词 氧化铜 氧化锆 催化剂 程序升温还原 CuO, ZrO_2, Catalyst, Temperature-programmed reduction (TPR), Interaction
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参考文献1

  • 1刘征,燃料化学学报,1990年,18卷,370页

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