摘要
合成了新配体１－Ｎ－（苯并咪唑－１－乙酰基）－４－苯基－３－氨基硫脲（ＢＰＭＳ），将其与Ｍｎ（Ⅱ）、Ｃｏ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｕ（Ⅱ）、Ｃｄ（Ⅱ）、Ｚｎ（Ⅱ）、ＵＯ２（Ⅱ）等金属的醋酸盐反应，合成了７个新配合物。所有化合物均经元素分析、ＩＲ、１ＨＮＭＲ和热重分析等表征。红外光谱表明，配体以四齿方式通过烯醇式羰基氧原子。
The synthesis of Mn(Ⅱ),Cu(Ⅱ),Co(Ⅱ),Zn(Ⅱ),Cd(Ⅱ),Ni(Ⅱ)and UO2(Ⅱ)complexes of new ligand 1-N-(benzimidazole-1-acetyl)-4-phenyl-3-thiosemicarbazides(BPMS)is reported.These compounds have been characterized by elemental analyses,IR,1H NMR and thermoanalyses.In frared spectra showed that the complex is a tetradentate coordination compound involving a carbonyl and a thiocarbonyl group connected with the adjacent nitrogen atoms(C=N groups)with each ligand binding to two metal centers.The resultant is proposed to be a polymer that grows through consecutive ligand-metal linkage.
出处
《合成化学》
CAS
CSCD
1996年第2期137-140,共4页
Chinese Journal of Synthetic Chemistry
基金
甘肃省自然科学基金
关键词
苯并咪唑
乙酰基
苯基
氨基硫脲
配合物
s:1-N-(Benzimidazole-1-acetyl)-4-phenyl-3-thiosemicarbazide(BPMS)
Complexes
Synthesis.
