摘要
采用自主研制的直流弧光放电等离子体CVD设备,以甲烷和氢气为气源,在YG 6硬质合金基体上制备出主显晶面为(100)、(111)以及纳米晶粒的金刚石薄膜涂层。SEM观测其晶体类型主要为立方体、八面体、立方八面体,其中以立方八面体为主。随着碳源气体浓度的增加,金刚石晶体的形态会呈现从八面体-立方八面体-立方体顺序转变的趋势;而薄膜的表面形貌呈现从主显(111)晶面-(111)与(100)晶面混杂-主显(100)晶面顺序转变的特征。此外,CVD金刚石薄膜中还存在有许多类似接触孪晶、贯穿孪晶、复合孪晶,以及球形或聚晶晶粒形态的晶体,并且多数孪晶属于类似{111}复合孪晶结构。
Polycrystalline diamond films with surface morphology of {100} and {111} facets were synthesized on a abraded cemented carbide tungsten tool from a gas mixture of methane and hydrogen by DC arc discharge plasma CVD . The morphology of diamond film observed by SEM. Showed that with increasing carbon gas concentration,the film morphology changed from {111} to {100} and the diamond particle shape varied from octahedron to cubic. There also exist a lot of twin-like particles and ballas type particles in the diamond films.
出处
《矿物岩石》
CAS
CSCD
北大核心
2005年第3期100-104,共5页
Mineralogy and Petrology
基金
四川省教育厅自然科学重点科研项目(编号2003A142)
四川省重点科技攻关项目(05GG021-001)
