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氮氧化物在湿法烟气脱硫过程中的作用 被引量:1

EFFECT OF NO_x ON WET FLUE GAS DESULFURIZATION PROCESS
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摘要 采用了气液鼓泡床反应器,以NaOH溶液为吸收液,在模拟烟气条件下对氮氧化物在湿法烟气脱硫过程中的作用进行了实验研究.结果表明,在吸收液为碱性的环境下,NO2的存在对脱硫率略有促进,SO2的存在则可显著增加脱硝率;在吸收液变乏且已呈酸性的环境下,NO2和SO2互相抑制彼此的脱除率;无论酸碱环境,NO和SO2对彼此脱除率的影响都很微弱.NO和NO2的存在对脱硫产物影响显著,NO2的存在促进了脱硫产物中硫酸盐的生成,碱性环境下尤其显著,而NO的存在抑制了脱硫产物中硫酸盐的生成. Wet flue gas desulfurization process is commonly adopted to control SO2 emission from coal-fired plants. Experiments were developed to investigate the effect of NOx on wet flue gas desulfurization process, with a gas-liquid bubbling-bed reactor and NaOH solution as absorbent, under simulated flue gas atmosphere. The results showed that the desulfurization rate increased slightly with the existence of NO2 and the removal rate of NO2 increased significantly with the existence of SO2, when the absorbent was alkaline; when the absorbent turned acidic, the existence of NO2 and SO2 decreased each other's removal rate; NO and SO2 has little influence on each other's removal rate, no matter the absorbent was alkaline or acidic; The existence of NO2 had a favorable effect on the formation of sulfate in desulfurization products, especially under alkaline atmosphere, while the existence of NO had a preventive effect.
出处 《煤炭转化》 CAS CSCD 北大核心 2005年第3期43-46,共4页 Coal Conversion
关键词 NO NO2 SO2 脱硫 脱硝 NO, NO2, SO2, desulfurization, denitrifaction
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参考文献8

  • 1马双忱,赵毅,李守信,王淑勤.联合脱除SO_2和 NO_x的烟气治理技术[J].华北电力大学学报(自然科学版),2000,27(3):87-92. 被引量:13
  • 2叶代启.烟气中氮氧化物污染的治理[J].环境保护科学,1999,25(4):1-4. 被引量:19
  • 3李平,卢冠忠,肖文德.面向21世纪的烟气脱硫脱氮一体化工艺[J].化学世界,2000,41(7):343-347. 被引量:18
  • 4Srivastava R K, Jozewicz W. Flue Gas Desulfurization: The State of the Art. Journal of the Air and Waste Management Association, 2001, 51(12): 1676-1688.
  • 5Zamansky V M, Ho L, Maly P M et al. Oxidation of NO to NO2 by Hydrogen Peroxide and its Mixtures with Methanol in Natural Gas and Coal Combustion Gases. Combustion Science and Technology, 1996,120: 255-272.
  • 6Siddiqi M A, Petersen J, Lucas K. A Study of the Effect of Nitrogen Dioxide on the Absorption of Sulfur Dioxide in Wet Flue Gas Cleaning Processes. Industrial and Engineering Chemistry Research, 2001, 40(9): 2116-2127.
  • 7Littlejohn D, Wang Y, Chang S G. Oxidation of Aqueous Sulfite Ion by Nitrogen Dioxide. Environmental Science and Technology, 1993, 27:2162-2167.
  • 8Littlejohn D, Chang S G. Modeling of the Chemistry of Wet Limestone Flue Gas Desulfurization Systems. Energy and Fuels,1991(5): 249-254.

二级参考文献29

  • 1赵由才,徐迪民,陈绍伟,李国建.钼硅酸化学吸收同时去除气流中的SO_2和NO_x[J].同济大学学报(自然科学版),1995,23(4):403-407. 被引量:14
  • 2[1]Lowell P S,Schwitzgebel K,Parsons T B,et al.Ind Eng Chem Process Des Develop,1971,10(3):384-390.
  • 3[2]Liu W,Sarofim A F,Flytzani-Stephanopoulos M.Applied Catalysis B,1994,4(2-3):167-186.
  • 4[3]Ma J X,Fang M,Lau N T.Journal of Catalysis,1996,158(1):251-259.
  • 5[5]Bosch H,Janssen F.Catalysis Today,1988,2(2):369-532.
  • 6[7]Blumrich S,Engler B.Catalysis Today,1993,17(1-2):301-310.
  • 7[8]Durrani SM,Environ Sci Technol,1994,28(2):89.
  • 8[9]Karisson HT,Rosenberg HS.Ind Eng Chem Process Des Develop,1984,23(4);808-814.
  • 9[10]Noyes R.Handbook of Pollution Control Processes.USA:Published by Noyes Publica-tions,1991.56-73.
  • 10[11]The NOXSO process.Applied Catalysis B,1994,5(1-2):NT-N10.

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